Phosphine, triphenyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
Proton affinity (review)972.8kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity940.4kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
7.44 ± 0.05PIPotapov, Rodionov, et al., 1974LLK
7.37 ± 0.01PEDebies and Rabalais, 1974LLK
7.83EIMuller and Fenderl, 1969RDSH
8.2 ± 0.05EIDistefano, Innorta, et al., 1968RDSH
7.36 ± 0.05PIVilesov and Zaitsev, 1964RDSH
7.80 ± 0.05PEIkuta, Kebarle, et al., 1982Vertical value; LBLHLM
7.97PEDaamen, Oskam, et al., 1980Vertical value; LLK
7.80PEStarzewski and Bock, 1976Vertical value; LLK
7.92PEWeiner, Lattman, et al., 1975Vertical value; LLK
7.85 ± 0.05PEDistefano, Pignataro, et al., 1975Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Potapov, Rodionov, et al., 1974
Potapov, V.K.; Rodionov, A.N.; Evlasheva, T.I.; Rogozhin, K.L., Photoionization of triphenyl derivatives of elements in group VB of the periodic table, High Energy Chem., 1974, 8, 486, In original 559. [all data]

Debies and Rabalais, 1974
Debies, T.P.; Rabalais, J.W., Photoelectron spectra of substituted benzenes. III. Bonding with Group V substituents, Inorg. Chem., 1974, 13, 308. [all data]

Muller and Fenderl, 1969
Muller, J.; Fenderl, K., Massenspektren und Ionisierungspotentiale von C5H5Mn(CO)2PX3-Komplexen, J. Organometal. Chem., 1969, 19, 123. [all data]

Distefano, Innorta, et al., 1968
Distefano, G.; Innorta, G.; Pignataro, S.; Foffani, A., Correlation between the ionization potentials of transition metal complexes and of the corresponding ligands, J. Organometal. Chem., 1968, 14, 165. [all data]

Vilesov and Zaitsev, 1964
Vilesov, F.I.; Zaitsev, V.M., Photoionization of phenyl derivatives of group 5 elements, Dokl. Akad. Nauk SSSR, 1964, 154, 886, In original 117. [all data]

Ikuta, Kebarle, et al., 1982
Ikuta, S.; Kebarle, P.; Bancroft, G.M.; Chan, T.; Puddephatt, R.J., Basicities of methyl-, methylphenyl-, and phenylphosphines in the gas phase, J. Am. Chem. Soc., 1982, 104, 5899. [all data]

Daamen, Oskam, et al., 1980
Daamen, H.; Oskam, A.; Stufkens, D.J., U.V. photoelectron (He I and He II) studies of M(CO)5PR3 (M = Cr, W and R = C6H11, C6H5, O-i-C3H7, OC6H5) and W(CO)5As(C6H5)3, Inorg. Chim. Acta, 1980, 38, 71. [all data]

Starzewski and Bock, 1976
Starzewski, K.A.O.; Bock, H., Photoelectron spectra and molecular properties. 58.1,2 Phosphorus ylides: Gas phase ionization potentials and charge distribution, J. Am. Chem. Soc., 1976, 98, 8486. [all data]

Weiner, Lattman, et al., 1975
Weiner, M.A.; Lattman, M.; Grim, S.O., Ultraviolet photoelectron spectra of some substituted triarylphosphines, J. Org. Chem., 1975, 40, 1292. [all data]

Distefano, Pignataro, et al., 1975
Distefano, G.; Pignataro, S.; Szepes, L.; Borossay, J., Photoelectron spectroscopy study of the triphenyl derivatives of the group V elements, J. Organomet. Chem., 1975, 102, 313. [all data]


Notes

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