3-Tetradecyne
- Formula: C14H26
- Molecular weight: 194.3562
- IUPAC Standard InChI: InChI=1S/C14H26/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-5,7,9-14H2,1-2H3
- IUPAC Standard InChIKey: DWWMJIDVLGUCDE-UHFFFAOYSA-N
- CAS Registry Number: 60212-32-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 3-C14H26
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Gas phase ion energetics data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.17 ± 0.02 | PI | Rang and Martinson, 1978 | LLK |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | OV-101 | 110. | 1437. | Kuningas, Rang, et al., 1990 | He; Column length: 50. m; Column diameter: 0.25 mm |
| Capillary | Apiezon L | 150. | 1415. | Rang, Kuningas, et al., 1976 | N2; Column length: 50. m; Column diameter: 0.25 mm |
| Capillary | Apiezon L | 170. | 1414. | Rang, Kuningas, et al., 1976 | N2; Column length: 50. m; Column diameter: 0.25 mm |
| Capillary | Apiezon L | 190. | 1414. | Rang, Kuningas, et al., 1976 | N2; Column length: 50. m; Column diameter: 0.25 mm |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | PEG-20M | 80. | 1576.4 | Orav, Kuningas, et al., 1993 | 100. m/0.25 mm/0.12 μm |
| Capillary | PEG-20M | 80. | 1596. | Orav, Kuningas, et al., 1993 | 100. m/0.25 mm/0.24 μm |
| Capillary | PEG-20M | 80. | 1596.5 | Orav, Kuningas, et al., 1993 | 60. m/0.32 mm/0.25 μm |
| Capillary | PEG 4000 | 110. | 1604. | Rang, Orav, et al., 1988 | |
| Capillary | PEG 4000 | 120. | 1604. | Rang, Orav, et al., 1988 | |
| Capillary | PEG 4000 | 140. | 1605. | Rang, Orav, et al., 1988 | |
| Capillary | PEG 4000 | 150. | 1604. | Rang, Orav, et al., 1988 | |
| Capillary | PEG 4000 | 160. | 1605. | Rang, Orav, et al., 1988 | |
| Capillary | PEG-20M | 70. | 1572.2 | Orav, Kuningas, et al., 1985 | Column length: 100. m; Column diameter: 0.25 mm |
| Capillary | PEG-20M | 80. | 1576.4 | Orav, Kuningas, et al., 1985 | Column length: 100. m; Column diameter: 0.25 mm |
| Capillary | PEG-20M | 80. | 1596. | Orav, Kuningas, et al., 1985 | Column length: 100. m; Column diameter: 0.25 mm |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rang and Martinson, 1978
Rang, S.; Martinson, E.,
Ionization potentials of unsaturated hydrocarbons. 3. n-Alkyunes C8-C12.,
Eesti. NSV Tead. Akad. Toim. Keem., 1978, 44. [all data]
Kuningas, Rang, et al., 1990
Kuningas, K.; Rang, S.; Kailas, T.,
Relationship between the structure and retention of n-alkenes and n-alkynes on silicone phases,
J. Chromatogr., 1990, 520, 137-148, https://doi.org/10.1016/0021-9673(90)85094-C
. [all data]
Rang, Kuningas, et al., 1976
Rang, S.; Kuningas, K.; Orav, A.; Eisen, O.,
Capillary gas chromatography of n-alkynes. I. Retention indices,
J. Chromatogr., 1976, 119, 451-460, https://doi.org/10.1016/S0021-9673(00)86807-7
. [all data]
Orav, Kuningas, et al., 1993
Orav, A.; Kuningas, K.; Rang, S.,
A comparison of different retention index systems with unsaturated and aromatic hydrocarbons in capillary gas chromatography on PEG 20MK,
Chromatographia, 1993, 37, 7/8, 411-414, https://doi.org/10.1007/BF02272257
. [all data]
Rang, Orav, et al., 1988
Rang, S.A.; Orav, A.E.; Kuningas, K.R.; Meister, A.E.; Strense, T.V.; Eisen, O.G.,
Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. [all data]
Orav, Kuningas, et al., 1985
Orav, A.; Kuningas, K.; Rang, S.; Eisen, O.,
Capillary gas chromatography of n-tridecenes, n-tetradecenes and C10-C14 n-alkynes on polyethylene glycol 20m of different polarity,
Eesti NSV Tead. Akad. Toim. Keem., 1985, 34, 2, 105-113. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
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