Stannane, tetraethyl-

• Formula: C₈H₂₀Sn
• Molecular weight: 234.954
• IUPAC Standard InChI: InChI=1S/4C2H5.Sn/c4*1-2;/h4*1H2,2H3; Copy

  
• IUPAC Standard InChIKey: RWWNQEOPUOCKGR-UHFFFAOYSA-N Copy
• CAS Registry Number: 597-64-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Tetraethyltin; Tetraethylstannane; (C2H5)4Sn; Tin, tetraethyl-; TET
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Reaction thermochemistry data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Tel'noi and Rabinovich, 1966
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1966, 40, 842. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Dillard, McNeill, et al., 1958
Dillard, C.R.; McNeill, E.H.; Simmons, D.E.; Yeldell, J.B., J. Am. Chem. Soc., 1958, 80, 3607. [all data]

Balandin, Klabunovskii, et al., 1957
Balandin, A.A.; Klabunovskii, E.I.; Kozina, M.P.; Ul'yanova, O.D., Izvest. Akad. Nauk SSSR Otdel. Khim. Nauk, 1957. [all data]

Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C., J. Chem. Soc., 1935, 39.. [all data]

Maslova, Rabinovich, et al., 1972
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A., Specific heat and phase transitions of some alkyl compounds of silicon, germanium, and tin, Tr. Khim. Khim. Tekhnol., 1972, (2), 44-50. [all data]

deRidder and Dijkstra, 1967
deRidder, J.J.; Dijkstra, G., Mass spectra of the tetramethyl and tetraethyl compounds of carbon, silicon, germanium, tin and lead, Rec. Trav. Chim., 1967, 86, 737. [all data]

Kochi, 1980
Kochi, J.K., The role of electron transfer and charge transfer in organometallic chemistry, Pure Appl. Chem., 1980, 52, 571. [all data]

Beltram, Fehlner, et al., 1980
Beltram, G.; Fehlner, T.P.; Mochida, K.; Kochi, J.K., UV photoelectron spectra of group IV alkyl hydrides, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 153. [all data]

Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G., Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy, J. Am. Chem. Soc., 1975, 97, 3682. [all data]

Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F., Electron impact determination of heats of formation and bond energies in triphenyltin compounds, Inorg. Chim. Acta, 1970, 4, 150. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  Cp,liquid	Constant pressure heat capacity of liquid
  ΔcH°liquid	Enthalpy of combustion of liquid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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