Stannane, tetraethyl-
- Formula: C8H20Sn
- Molecular weight: 234.954
- IUPAC Standard InChIKey: RWWNQEOPUOCKGR-UHFFFAOYSA-N
- CAS Registry Number: 597-64-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetraethyltin; Tetraethylstannane; (C2H5)4Sn; Tin, tetraethyl-; TET
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -10.0 ± 0.62 | kcal/mol | Review | Martinho Simões | Selected data. |
ΔfH°gas | -15.6 ± 1.5 | kcal/mol | Review | Martinho Simões | |
ΔfH°gas | -10.5 ± 2.0 | kcal/mol | Review | Martinho Simões | |
ΔfH°gas | -14.5 ± 2.0 | kcal/mol | Review | Martinho Simões | |
ΔfH°gas | -40.51 | kcal/mol | Review | Martinho Simões |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(l) + (l) = C2H5Cl3Sn (l) + (l)
By formula: C8H20Sn (l) + Cl4Sn (l) = C2H5Cl3Sn (l) + C6H15ClSn (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -22.6 ± 1.1 | kcal/mol | RSC and EST | Nash, Skinner, et al., 1965 |
By formula: 3C8H20Sn (l) + Cl4Sn (l) = 4C6H15ClSn (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -45.3 ± 2.2 | kcal/mol | RSC and EST | Nash, Skinner, et al., 1965 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.3 | EI | deRidder and Dijkstra, 1967 | RDSH |
8.93 | PE | Kochi, 1980 | Vertical value; LLK |
9.0 | PE | Beltram, Fehlner, et al., 1980 | Vertical value; LLK |
8.87 | PE | Hosomi and Traylor, 1975 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C2H5Sn+ | 14.4 | ? | EI | deRidder and Dijkstra, 1967 | RDSH |
C2H7Sn+ | 13.0 | ? | EI | deRidder and Dijkstra, 1967 | RDSH |
C4H11Sn+ | 12.1 | ? | EI | deRidder and Dijkstra, 1967 | RDSH |
C6H15Sn+ | 8.70 ± 0.09 | ? | EI | Chambers and Glockling, 1970 | RDSH |
C6H15Sn+ | 10.9 | ? | EI | deRidder and Dijkstra, 1967 | RDSH |
SnH+ | 16.7 | ? | EI | deRidder and Dijkstra, 1967 | RDSH |
Sn+ | 17.1 | ? | EI | deRidder and Dijkstra, 1967 | RDSH |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Gas Phase Spectrum
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Additional Data
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Owner | NIST Standard Reference Data Program Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Sadtler Research Labs Under US-EPA Contract |
State | gas |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Chemical Concepts |
NIST MS number | 162550 |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F.,
Trans. Faraday Soc., 1965, 61, 640. [all data]
deRidder and Dijkstra, 1967
deRidder, J.J.; Dijkstra, G.,
Mass spectra of the tetramethyl and tetraethyl compounds of carbon, silicon, germanium, tin and lead,
Rec. Trav. Chim., 1967, 86, 737. [all data]
Kochi, 1980
Kochi, J.K.,
The role of electron transfer and charge transfer in organometallic chemistry,
Pure Appl. Chem., 1980, 52, 571. [all data]
Beltram, Fehlner, et al., 1980
Beltram, G.; Fehlner, T.P.; Mochida, K.; Kochi, J.K.,
UV photoelectron spectra of group IV alkyl hydrides,
J. Electron Spectrosc. Relat. Phenom., 1980, 18, 153. [all data]
Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G.,
Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy,
J. Am. Chem. Soc., 1975, 97, 3682. [all data]
Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F.,
Electron impact determination of heats of formation and bond energies in triphenyltin compounds,
Inorg. Chim. Acta, 1970, 4, 150. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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