Diethyl sulfone

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-429.3 ± 2.6kJ/molCcbMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -428. ± 3. kJ/mol; Hfusion=3.4±0.4 kcal/mol,Heat of comb. corrected for constant pressure

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-515.51 ± 0.67kJ/molCcbMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -513.8 ± 0.8 kJ/mol; Hfusion=3.4±0.4 kcal/mol,Heat of comb. corrected for constant pressure
Quantity Value Units Method Reference Comment
Δcsolid-3090.0 ± 0.42kJ/molCcbMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -3091.3 ± 0.42 kJ/mol; Hfusion=3.4±0.4 kcal/mol,Heat of comb. corrected for constant pressure

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tfus345.KN/ADyer, Harris, et al., 1982Uncertainty assigned by TRC = 2. K
Tfus347.KN/ABoehme and Sitorus, 1972Uncertainty assigned by TRC = 2. K
Tfus346.7KN/AHall and Robinson, 1964Uncertainty assigned by TRC = 1.5 K
Tfus345.2KN/AMackle and O'Hare, 1961Uncertainty assigned by TRC = 1. K
Tfus342.2KN/AMcallan, Cullum, et al., 1951Uncertainty assigned by TRC = 0.5 K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.96 ± 0.03PIEvlasheva, Puchkova, et al., 1975LLK

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW- 941
NIST MS number 239660

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 5.-Heats of combustion, formation, fusion, vaporization and atomization of eleven aliphatic sulphones, Trans. Faraday Soc., 1961, 57, 1070-1074. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Dyer, Harris, et al., 1982
Dyer, J.C.; Harris, D.L.; Evans, S.A., Oxygen-17 Nulcear Magnetic RFesonacne SPtroscopy of Sulfoxides and Sulfones. Alkyl Substituent Induced Chemical Shifts, J. Org. Chem., 1982, 47, 3660-4. [all data]

Boehme and Sitorus, 1972
Boehme, V.H.; Sitorus, U., Oxidation of Thioethers to Sulfones with Hydrogen Peroxide in Alkaline Solution, Chem.-Ztg., 1972, 96, 37-8. [all data]

Hall and Robinson, 1964
Hall, S.K.; Robinson, E.A., The Sulphuric Acid Solvent System. Part VI. The Basicities of Compounds Containing Sulphur-Oxyten Bonds, Can. J. Chem., 1964, 42, 1113-22. [all data]

Mcallan, Cullum, et al., 1951
Mcallan, D.T.; Cullum, T.V.; Dean, R.A.; Fidler, F.A., The Preparation and Properties of Sulfur Compounds Related to Petroleum I. The Dialkyl Sulfides and Disulfides, J. Am. Chem. Soc., 1951, 73, 3627-32. [all data]

Evlasheva, Puchkova, et al., 1975
Evlasheva, T.I.; Puchkova, V.V.; Potapov, V.K.; Gur'yanova, E.N., Ionisation potentials and electron-donating properties of sulphones, Russ. J. Phys. Chem., 1975, 49, 453. [all data]


Notes

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