Stannane, tetraphenyl-

• Formula: C₂₄H₂₀Sn
• Molecular weight: 427.126
• IUPAC Standard InChI: InChI=1S/4C6H5.Sn/c4*1-2-4-6-5-3-1;/h4*1-5H; Copy

  
• IUPAC Standard InChIKey: CRHIAMBJMSSNNM-UHFFFAOYSA-N Copy
• CAS Registry Number: 595-90-4
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Tetraphenylstannane; Tetraphenyltin; Tin, tetraphenyl-,
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • IR Spectrum
  • UV/Visible spectrum
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Enthalpy of sublimation

Enthalpy of fusion

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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Additional Data

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G., J. Chem. Thermodyn., 1969, 1, 393. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1965
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1965, 39, 1239. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Pope and Skinner, 1964
Pope, A.E.; Skinner, H.A., Trans. Faraday Soc., 1964, 60, 1402. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Birr, 1962
Birr, K.-H., Z. Anorg. Allg. Chem., 1962, 315, 175. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]

Adams and Carson, 1969
Adams, G.P.; Carson, A.S., The Enthalpy of COmbustion of Organimetallic Compounds Measured with a Vacuum-jacketed Aneroud Calorimeter. The Enthalpy of Formation of Tin Tetraphenyl, J. Chem. Thermodyn., 1969, 1, 393-6. [all data]

Sangster and Irvine, 1956
Sangster, R.C.; Irvine, J.W., Study of Organic Scintillators, J. Chem. Phys., 1956, 24, 670. [all data]

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931, 2
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Adams, Carson, et al., 1969, 2
Adams, G.P.; Carson, A.S.; Laye, P.G., The enthalpy of combustion of organometallic compounds measured with a vacuum-jacketed aneroid calorimeter The enthalpy of formation of tin tetraphenyl, The Journal of Chemical Thermodynamics, 1969, 1, 4, 393-396, https://doi.org/10.1016/0021-9614(69)90069-X . [all data]

Newkirk, 1972
Newkirk, Herbert W., Piezoelectric organometallic crystal: Growth and properties of tetraphenylsilicon, -germanium, -ti and -lead, Journal of Organometallic Chemistry, 1972, 44, 2, 263-271, https://doi.org/10.1016/S0022-328X(00)82914-9 . [all data]

Marcus and Loewenschuss, 1986
Marcus, Yizhak; Loewenschuss, Aharon, Entropies of tetrahedral M---phenyl species, J. Chem. Soc., Faraday Trans. 1, 1986, 82, 3, 993, https://doi.org/10.1039/f19868200993 . [all data]

Keiser and Kana'an, 1969
Keiser, D.; Kana'an, A.S., J. Phys. Chem., 1969, 73, 4264. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Keiser and Kana'an, 1969, 2
Keiser, D.; Kana'an, A.S., Enthalpy and entropy of sublimation of tetraphenyltin and hexaphenylditin. Bond dissociation energy of Sn-C and Sn-Sn, J. Phys. Chem., 1969, 73, 12, 4264-4269, https://doi.org/10.1021/j100846a038 . [all data]

Vitoria and Walkley, 1969
Vitoria, M.; Walkley, John, Studies in regular solution theory. Part 1.?Solubolity studies of tetraphenyltin in simple non-polar solvents, Trans. Faraday Soc., 1969, 65, 57, https://doi.org/10.1039/tf9696500057 . [all data]

Novak and Potts, 1984
Novak, I.; Potts, A.W., The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives, J. Organomet. Chem., 1984, 262, 17. [all data]

Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L., Photoionization of certain aromatic heteroorganic compounds, High Energy Chem., 1973, 7, 249, In original 278. [all data]

Occolowitz, Lett. 1966
Occolowitz, J.L., Electron impact fragmentation of some organotin compounds, Tetrahedron, Lett. 1966, 5291. [all data]

Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F., Electron impact determination of heats of formation and bond energies in triphenyltin compounds, Inorg. Chim. Acta, 1970, 4, 150. [all data]

Lang (editor), 1968
Lang (editor), L., Absorption Spectra in the Ultraviolet and Visible Region, 1968, 11, 19. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  Cp,solid	Constant pressure heat capacity of solid
  Tfus	Fusion (melting) point
  ΔcH°solid	Enthalpy of combustion of solid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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