Stannane, tetraphenyl-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas700. ± 400.kJ/molAVGN/AAverage of 6 values; Individual data points

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid600. ± 400.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δcsolid-13293.4 ± 5.4kJ/molCC-SBAdams, Carson, et al., 1969Please also see Pedley and Rylance, 1977.; MS
Δcsolid-13368. ± 13.kJ/molCC-SBTel'noi and Rabinovich, 1965Please also see Cox and Pilcher, 1970.; MS
Δcsolid-13295.6 ± 3.4kJ/molCC-SBPope and Skinner, 1964Please also see Cox and Pilcher, 1970.; MS
Δcsolid-13566.6 ± 7.1kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Cox and Pilcher, 1970.; MS
Δcsolid-13839. ± 13.kJ/molCC-SBBirr, 1962MS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
426.3298.5Smith and Andrews, 1931T = 102 to 346 K. Value is unsmoothed experimental datum.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tfus501.KN/AAdams and Carson, 1969Uncertainty assigned by TRC = 2. K; TRC
Tfus503.2KN/ASangster and Irvine, 1956Uncertainty assigned by TRC = 4. K; TRC
Tfus499.1KN/AForward, Bowden, et al., 1949Uncertainty assigned by TRC = 0.7 K; TRC
Tfus499.15KN/ASmith and Andrews, 1931, 2Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δsub161.1 ± 4.2kJ/molN/APilcher and Skinner, 1983See also Adams, Carson, et al., 1969, 2.; AC
Δsub59.5kJ/molN/ANewkirk, 1972See also Marcus and Loewenschuss, 1986.; AC
Δsub161.1 ± 4.2kJ/molCC-SBKeiser and Kana'an, 1969MS

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
151.7427.AStephenson and Malanowski, 1987Based on data from 393. to 461. K.; AC
152.5 ± 0.6428. to 454.TEKeiser and Kana'an, 1969, 2AC
151.8 ± 1.1393. to 461.MEKeiser and Kana'an, 1969, 2AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
37.2502.2DSCVitoria and Walkley, 1969AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.1PENovak and Potts, 1984LBLHLM
8.34 ± 0.03PIRodionov, Potapov, et al., 1973LLK
9.04PENovak and Potts, 1984Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H5Sn+16.1 ± 0.5?EIOccolowitz, Lett. 1966RDSH
C12H10Sn+9.1 ± 0.2?EIOccolowitz, Lett. 1966RDSH
C18H15Sn+9.6 ± 0.2?EIChambers and Glockling, 1970RDSH
C18H15Sn+10.1 ± 0.2?EIOccolowitz, Lett. 1966RDSH
Sn+9.4 ± 0.2?EIOccolowitz, Lett. 1966RDSH

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

IR spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

View scan of original (hardcopy) spectrum.

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner Copyright (C) 1987 by the Coblentz Society
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin DOW CORNING CORP.
Source reference COBLENTZ NO. 5579
Date 1966/05/10
Name(s) tetraphenylstannane
State SOLID (SPLIT MULL)
Instrument PERKIN-ELMER 521 (GRATING)
Instrument parameters FILTERS AT 3150, 2500, 2000, 1150, 700, 410. GRATING CHANGES: 2000, 630
Resolution 2
Melting point 228 C

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 163437

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G., J. Chem. Thermodyn., 1969, 1, 393. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1965
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1965, 39, 1239. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Pope and Skinner, 1964
Pope, A.E.; Skinner, H.A., Trans. Faraday Soc., 1964, 60, 1402. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Birr, 1962
Birr, K.-H., Z. Anorg. Allg. Chem., 1962, 315, 175. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]

Adams and Carson, 1969
Adams, G.P.; Carson, A.S., The Enthalpy of COmbustion of Organimetallic Compounds Measured with a Vacuum-jacketed Aneroud Calorimeter. The Enthalpy of Formation of Tin Tetraphenyl, J. Chem. Thermodyn., 1969, 1, 393-6. [all data]

Sangster and Irvine, 1956
Sangster, R.C.; Irvine, J.W., Study of Organic Scintillators, J. Chem. Phys., 1956, 24, 670. [all data]

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931, 2
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Adams, Carson, et al., 1969, 2
Adams, G.P.; Carson, A.S.; Laye, P.G., The enthalpy of combustion of organometallic compounds measured with a vacuum-jacketed aneroid calorimeter The enthalpy of formation of tin tetraphenyl, The Journal of Chemical Thermodynamics, 1969, 1, 4, 393-396, https://doi.org/10.1016/0021-9614(69)90069-X . [all data]

Newkirk, 1972
Newkirk, Herbert W., Piezoelectric organometallic crystal: Growth and properties of tetraphenylsilicon, -germanium, -ti and -lead, Journal of Organometallic Chemistry, 1972, 44, 2, 263-271, https://doi.org/10.1016/S0022-328X(00)82914-9 . [all data]

Marcus and Loewenschuss, 1986
Marcus, Yizhak; Loewenschuss, Aharon, Entropies of tetrahedral M---phenyl species, J. Chem. Soc., Faraday Trans. 1, 1986, 82, 3, 993, https://doi.org/10.1039/f19868200993 . [all data]

Keiser and Kana'an, 1969
Keiser, D.; Kana'an, A.S., J. Phys. Chem., 1969, 73, 4264. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Keiser and Kana'an, 1969, 2
Keiser, D.; Kana'an, A.S., Enthalpy and entropy of sublimation of tetraphenyltin and hexaphenylditin. Bond dissociation energy of Sn-C and Sn-Sn, J. Phys. Chem., 1969, 73, 12, 4264-4269, https://doi.org/10.1021/j100846a038 . [all data]

Vitoria and Walkley, 1969
Vitoria, M.; Walkley, John, Studies in regular solution theory. Part 1.?Solubolity studies of tetraphenyltin in simple non-polar solvents, Trans. Faraday Soc., 1969, 65, 57, https://doi.org/10.1039/tf9696500057 . [all data]

Novak and Potts, 1984
Novak, I.; Potts, A.W., The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives, J. Organomet. Chem., 1984, 262, 17. [all data]

Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L., Photoionization of certain aromatic heteroorganic compounds, High Energy Chem., 1973, 7, 249, In original 278. [all data]

Occolowitz, Lett. 1966
Occolowitz, J.L., Electron impact fragmentation of some organotin compounds, Tetrahedron, Lett. 1966, 5291. [all data]

Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F., Electron impact determination of heats of formation and bond energies in triphenyltin compounds, Inorg. Chim. Acta, 1970, 4, 150. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References