Stannane, tetraphenyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas700. ± 400.kJ/molAVGN/AAverage of 6 values; Individual data points

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid600. ± 400.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δcsolid-13293.4 ± 5.4kJ/molCC-SBAdams, Carson, et al., 1969Please also see Pedley and Rylance, 1977.; MS
Δcsolid-13368. ± 13.kJ/molCC-SBTel'noi and Rabinovich, 1965Please also see Cox and Pilcher, 1970.; MS
Δcsolid-13295.6 ± 3.4kJ/molCC-SBPope and Skinner, 1964Please also see Cox and Pilcher, 1970.; MS
Δcsolid-13566.6 ± 7.1kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Cox and Pilcher, 1970.; MS
Δcsolid-13839. ± 13.kJ/molCC-SBBirr, 1962MS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
426.3298.5Smith and Andrews, 1931T = 102 to 346 K. Value is unsmoothed experimental datum.; DH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.1PENovak and Potts, 1984LBLHLM
8.34 ± 0.03PIRodionov, Potapov, et al., 1973LLK
9.04PENovak and Potts, 1984Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H5Sn+16.1 ± 0.5?EIOccolowitz, Lett. 1966RDSH
C12H10Sn+9.1 ± 0.2?EIOccolowitz, Lett. 1966RDSH
C18H15Sn+9.6 ± 0.2?EIChambers and Glockling, 1970RDSH
C18H15Sn+10.1 ± 0.2?EIOccolowitz, Lett. 1966RDSH
Sn+9.4 ± 0.2?EIOccolowitz, Lett. 1966RDSH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adams, Carson, et al., 1969
Adams, G.P.; Carson, A.S.; Laye, P.G., J. Chem. Thermodyn., 1969, 1, 393. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1965
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1965, 39, 1239. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Pope and Skinner, 1964
Pope, A.E.; Skinner, H.A., Trans. Faraday Soc., 1964, 60, 1402. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Birr, 1962
Birr, K.-H., Z. Anorg. Allg. Chem., 1962, 315, 175. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]

Novak and Potts, 1984
Novak, I.; Potts, A.W., The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives, J. Organomet. Chem., 1984, 262, 17. [all data]

Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L., Photoionization of certain aromatic heteroorganic compounds, High Energy Chem., 1973, 7, 249, In original 278. [all data]

Occolowitz, Lett. 1966
Occolowitz, J.L., Electron impact fragmentation of some organotin compounds, Tetrahedron, Lett. 1966, 5291. [all data]

Chambers and Glockling, 1970
Chambers, D.B.; Glockling, F., Electron impact determination of heats of formation and bond energies in triphenyltin compounds, Inorg. Chim. Acta, 1970, 4, 150. [all data]


Notes

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