Plumbane, tetraphenyl-
- Formula: C24H20Pb
- Molecular weight: 515.6
- IUPAC Standard InChIKey: WBJSMHDYLOJVKC-UHFFFAOYSA-N
- CAS Registry Number: 595-89-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Tetraphenyllead; Tetraphenylplumbane; Lead, tetraphenyl-,
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 674. ± 15. | kJ/mol | Review | Martinho Simões | Selected data |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 515. ± 15. | kJ/mol | Review | Martinho Simões | Selected data |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -13036. ± 15. | kJ/mol | CC-RB | Carson, Laye, et al., 1972 | Please also see Pedley and Rylance, 1977. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 194.6 ± 6.3 | kJ/mol | E | Pilcher and Skinner, 1983 | See also Carson, Laye, et al., 1972, 2.; AC |
ΔsubH° | 159. ± 1. | kJ/mol | CC-RB | Kana'an and Morrison, 1977 | MS |
ΔsubH° | 159. ± 1. | kJ/mol | ME,TE | Kana'an and Morrison, 1977, 2 | Based on data from 412. to 474. K.; AC |
ΔsubH° | 82.8 | kJ/mol | N/A | Newkirk, 1972 | AC |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
151. | 446. | Stephenson and Malanowski, 1987 | Based on data from 412. to 480. K.; AC |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.0 | PE | Novak and Potts, 1984 | LBLHLM |
8.95 | PE | Novak and Potts, 1984 | Vertical value; LBLHLM |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Carson, Laye, et al., 1972
Carson, A.S.; Laye, P.G.; Spencer, J.A.; Steele, W.V.,
J. Chem. Thermodyn., 1972, 4, 783. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Carson, Laye, et al., 1972, 2
Carson, A.S.; Laye, P.G.; Spencer, J.A.; Steele, W.V.,
The enthalpy of combustion of organo-metallic compounds measured with a vacuum-jacketed rotating aneroid calorimeter. The enthalpy of formation of lead tetraphenyl,
The Journal of Chemical Thermodynamics, 1972, 4, 5, 783-787, https://doi.org/10.1016/0021-9614(72)90052-3
. [all data]
Kana'an and Morrison, 1977
Kana'an, A.S.; Morrison, T.I.,
J. Chem. Thermodyn., 1977, 9, 423. [all data]
Kana'an and Morrison, 1977, 2
Kana'an, Adli S.; Morrison, T.I.,
Enthalpy and entropy of sublimation of tetraphenyl plumbane the bond dissociation energy of Pb«58872»C,
The Journal of Chemical Thermodynamics, 1977, 9, 5, 423-429, https://doi.org/10.1016/0021-9614(77)90142-2
. [all data]
Newkirk, 1972
Newkirk, Herbert W.,
Piezoelectric organometallic crystal: Growth and properties of tetraphenylsilicon, -germanium, -ti and -lead,
Journal of Organometallic Chemistry, 1972, 44, 2, 263-271, https://doi.org/10.1016/S0022-328X(00)82914-9
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Novak and Potts, 1984
Novak, I.; Potts, A.W.,
The UV gas-phase photoelectron spectra of Group IVB tetraphenyl derivatives,
J. Organomet. Chem., 1984, 262, 17. [all data]
Notes
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- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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