Stibine, trimethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas32. ± 25.kJ/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap32.5 ± 0.01kJ/molN/AFulem, Moravek, et al., 2010Based on data from 249. to 296. K.; AC
Δvap31.4 ± 1.3kJ/molCC-SBBamford, Levi, et al., 1946Please also see Long and Sackman, 1955.; MS

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.7PEElbel, Dieck, et al., 1982LBLHLM
8.04 ± 0.16EIWinters and Kiser, 1967RDSH
8.48PEElbel, Dieck, et al., 1982Vertical value; LBLHLM
8.48PEElbel, Bergmann, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHSb+13.7 ± 0.4?EIWinters and Kiser, 1967RDSH
CH2Sb+15.1 ± 0.2?EIWinters and Kiser, 1967RDSH
CH3Sb+14.3 ± 0.2?EIWinters and Kiser, 1967RDSH
CH4Sb+13.4 ± 0.3?EIWinters and Kiser, 1967RDSH
C2H4Sb+12.6 ± 0.3?EIWinters and Kiser, 1967RDSH
C2H6Sb+10.5 ± 0.2CH3EIWinters and Kiser, 1967RDSH
SbH+14.5 ± 0.5?EIWinters and Kiser, 1967RDSH
SbH2+13.7 ± 0.2?EIWinters and Kiser, 1967RDSH
Sb+14.8 ± 0.4?EIWinters and Kiser, 1967RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Fulem, Moravek, et al., 2010
Fulem, Michal; Moravek, Pavel; Pangrac, Jiri; Hulicius, Eduard; Simecek, Tomislav; Ruzicka, Kvetoslav; Ruzicka, Vlastimil; Kozyrkin, Boris; Shatunov, Valery, Vapor Pressure of Trimethylantimony and tert -Butyldimethylantimony, J. Chem. Eng. Data, 2010, 55, 1, 362-365, https://doi.org/10.1021/je900372v . [all data]

Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M., J. Chem. Soc., 1946, 468.. [all data]

Long and Sackman, 1955
Long, L.H.; Sackman, J.F., Research (Correspondence), 1955, 8, 523. [all data]

Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R., Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect, J. Fluorine Chem., 1982, 19, 349. [all data]

Winters and Kiser, 1967
Winters, R.E.; Kiser, R.W., Ionization and fragmentation of dimethylzinc, trimethylaluminum, and trimethylantimony, J. Organometal. Chem., 1967, 10, 7. [all data]

Elbel, Bergmann, et al., 1974
Elbel, S.; Bergmann, H.; EnBlin, W., Photoelectron spectra of the trimethyl compounds of the Group V elements, J. Chem. Soc. Faraday Trans. 2., 1974, 70, 555. [all data]


Notes

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