Stibine, trimethyl-
- Formula: C3H9Sb
- Molecular weight: 166.864
- IUPAC Standard InChIKey: PORFVJURJXKREL-UHFFFAOYSA-N
- CAS Registry Number: 594-10-5
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Trimethylantimony; Trimethylstibine; (CH3)3Sb
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Gas phase thermochemistry data
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 32. ± 25. | kJ/mol | Review | Martinho Simões |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.7 | PE | Elbel, Dieck, et al., 1982 | LBLHLM |
8.04 ± 0.16 | EI | Winters and Kiser, 1967 | RDSH |
8.48 | PE | Elbel, Dieck, et al., 1982 | Vertical value; LBLHLM |
8.48 | PE | Elbel, Bergmann, et al., 1974 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CHSb+ | 13.7 ± 0.4 | ? | EI | Winters and Kiser, 1967 | RDSH |
CH2Sb+ | 15.1 ± 0.2 | ? | EI | Winters and Kiser, 1967 | RDSH |
CH3Sb+ | 14.3 ± 0.2 | ? | EI | Winters and Kiser, 1967 | RDSH |
CH4Sb+ | 13.4 ± 0.3 | ? | EI | Winters and Kiser, 1967 | RDSH |
C2H4Sb+ | 12.6 ± 0.3 | ? | EI | Winters and Kiser, 1967 | RDSH |
C2H6Sb+ | 10.5 ± 0.2 | CH3 | EI | Winters and Kiser, 1967 | RDSH |
SbH+ | 14.5 ± 0.5 | ? | EI | Winters and Kiser, 1967 | RDSH |
SbH2+ | 13.7 ± 0.2 | ? | EI | Winters and Kiser, 1967 | RDSH |
Sb+ | 14.8 ± 0.4 | ? | EI | Winters and Kiser, 1967 | RDSH |
Mass spectrum (electron ionization)
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 6352 |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R.,
Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect,
J. Fluorine Chem., 1982, 19, 349. [all data]
Winters and Kiser, 1967
Winters, R.E.; Kiser, R.W.,
Ionization and fragmentation of dimethylzinc, trimethylaluminum, and trimethylantimony,
J. Organometal. Chem., 1967, 10, 7. [all data]
Elbel, Bergmann, et al., 1974
Elbel, S.; Bergmann, H.; EnBlin, W.,
Photoelectron spectra of the trimethyl compounds of the Group V elements,
J. Chem. Soc. Faraday Trans. 2., 1974, 70, 555. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), References
- Symbols used in this document:
AE Appearance energy ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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