Stibine, trimethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas32. ± 25.kJ/molReviewMartinho Simões 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.7PEElbel, Dieck, et al., 1982LBLHLM
8.04 ± 0.16EIWinters and Kiser, 1967RDSH
8.48PEElbel, Dieck, et al., 1982Vertical value; LBLHLM
8.48PEElbel, Bergmann, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHSb+13.7 ± 0.4?EIWinters and Kiser, 1967RDSH
CH2Sb+15.1 ± 0.2?EIWinters and Kiser, 1967RDSH
CH3Sb+14.3 ± 0.2?EIWinters and Kiser, 1967RDSH
CH4Sb+13.4 ± 0.3?EIWinters and Kiser, 1967RDSH
C2H4Sb+12.6 ± 0.3?EIWinters and Kiser, 1967RDSH
C2H6Sb+10.5 ± 0.2CH3EIWinters and Kiser, 1967RDSH
SbH+14.5 ± 0.5?EIWinters and Kiser, 1967RDSH
SbH2+13.7 ± 0.2?EIWinters and Kiser, 1967RDSH
Sb+14.8 ± 0.4?EIWinters and Kiser, 1967RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
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NIST MS number 6352

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References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R., Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect, J. Fluorine Chem., 1982, 19, 349. [all data]

Winters and Kiser, 1967
Winters, R.E.; Kiser, R.W., Ionization and fragmentation of dimethylzinc, trimethylaluminum, and trimethylantimony, J. Organometal. Chem., 1967, 10, 7. [all data]

Elbel, Bergmann, et al., 1974
Elbel, S.; Bergmann, H.; EnBlin, W., Photoelectron spectra of the trimethyl compounds of the Group V elements, J. Chem. Soc. Faraday Trans. 2., 1974, 70, 555. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), References