Stibine, trimethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas32. ± 25.kJ/molReviewMartinho Simões 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Stibine, trimethyl- (g) = C2H6Sb (g) + Methane (g)

By formula: C3H9Sb (g) = C2H6Sb (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr247. to 259.kJ/molN/ASmith and Patrick, 1983 
Δr255. ± 17.kJ/molN/AMcMillen and Golden, 1982 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.7PEElbel, Dieck, et al., 1982LBLHLM
8.04 ± 0.16EIWinters and Kiser, 1967RDSH
8.48PEElbel, Dieck, et al., 1982Vertical value; LBLHLM
8.48PEElbel, Bergmann, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHSb+13.7 ± 0.4?EIWinters and Kiser, 1967RDSH
CH2Sb+15.1 ± 0.2?EIWinters and Kiser, 1967RDSH
CH3Sb+14.3 ± 0.2?EIWinters and Kiser, 1967RDSH
CH4Sb+13.4 ± 0.3?EIWinters and Kiser, 1967RDSH
C2H4Sb+12.6 ± 0.3?EIWinters and Kiser, 1967RDSH
C2H6Sb+10.5 ± 0.2CH3EIWinters and Kiser, 1967RDSH
SbH+14.5 ± 0.5?EIWinters and Kiser, 1967RDSH
SbH2+13.7 ± 0.2?EIWinters and Kiser, 1967RDSH
Sb+14.8 ± 0.4?EIWinters and Kiser, 1967RDSH

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R., Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect, J. Fluorine Chem., 1982, 19, 349. [all data]

Winters and Kiser, 1967
Winters, R.E.; Kiser, R.W., Ionization and fragmentation of dimethylzinc, trimethylaluminum, and trimethylantimony, J. Organometal. Chem., 1967, 10, 7. [all data]

Elbel, Bergmann, et al., 1974
Elbel, S.; Bergmann, H.; EnBlin, W., Photoelectron spectra of the trimethyl compounds of the Group V elements, J. Chem. Soc. Faraday Trans. 2., 1974, 70, 555. [all data]


Notes

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