1-Bromo-1-chloroethane

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1-Bromo-1-chloroethane = Hydrogen bromide + Ethene, chloro-

By formula: C2H4BrCl = HBr + C2H3Cl

Quantity Value Units Method Reference Comment
Δr83.3 ± 0.8kJ/molEqkBusheva, Levanova, et al., 1980gas phase; Dehydrohalogenation

1-Bromo-1-chloroethane = Vinyl bromide + Hydrogen chloride

By formula: C2H4BrCl = C2H3Br + HCl

Quantity Value Units Method Reference Comment
Δr66. ± 2.kJ/molEqkBusheva, Levanova, et al., 1980gas phase; Dehydrohalogenation

21-Bromo-1-chloroethane = Ethane, 1,1-dibromo- + Ethane, 1,1-dichloro-

By formula: 2C2H4BrCl = C2H4Br2 + C2H4Cl2

Quantity Value Units Method Reference Comment
Δr7.9 ± 0.4kJ/molEqkBusheva, Levanova, et al., 1980gas phase; Dehydrohalogenation

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.37PEBerman, Anicich, et al., 1979LLK
10.42PIBerman, Anicich, et al., 1979LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H4Br+10.57?PIBerman, Anicich, et al., 1979LLK
C2H4Cl+10.52?PIBerman, Anicich, et al., 1979LLK

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Busheva, Levanova, et al., 1980
Busheva, L.I.; Levanova, S.V.; Rodova, R.M.; Rozhnov, A.M., Thermocatalytic reactions of 1,1-bromochloroethane, Russ. J. Phys. Chem. (Engl. Transl.), 1980, 54, 1403-1404. [all data]

Berman, Anicich, et al., 1979
Berman, D.W.; Anicich, V.; Beauchamp, J.L., Stabilities of isomeric halonium ions C2H4X+ (X = Cl, Br) by photoionization mass spectrometry iand on cyclotron resonance spectroscopy. General considerations of the relative stabilities of cyclic and acyclic isomeric onium ions, J. Am. Chem. Soc., 1979, 101, 1239. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References