e-Diazene, bis(bicyclo[2.2.1]hept-1-yl)-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C14H22N2 = C14H22N2

By formula: C14H22N2 = C14H22N2

Quantity Value Units Method Reference Comment
Δr-67.9 ± 3.8kJ/molKinSchmittel and Ruchardt, 1987solid phase; solvent: Mesitylene
Δr-81. ± 2.kJ/molEqkSchmittel, Schultz, et al., 1981liquid phase; solvent: Dimethyl formamide
Δr-79. ± 2.kJ/molEqkSchmittel, Schultz, et al., 1981liquid phase; solvent: Dodecane

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

IE (eV) Method Reference Comment
8.24PEEngel, Gerth, et al., 1988Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schmittel and Ruchardt, 1987
Schmittel, M.; Ruchardt, C., Stereoisomerization and homolytic decomposition of cis and trans bridgehead diazenes, J. Am. Chem. Soc., 1987, 109, 2750-2759. [all data]

Schmittel, Schultz, et al., 1981
Schmittel, M.; Schultz, A.; Ruchardt, C.; Hadicke, E., Aliphatic azo compounds. XIII. cis- and trans-1-Azonorbornane, Chem. Ber., 1981, 114, 3533-3548. [all data]

Engel, Gerth, et al., 1988
Engel, P.S.; Gerth, D.B.; Keys, D.E.; Scholz, J.N.; Houk, K.N.; Rozeboom, M.D.; Eaton, T.A.; Glass, R.S.; Broeker, J.L., Ionization potentials of some azoalkanes by photoelectron spectroscopy, Tetrahedron, 1988, 44, 6811. [all data]


Notes

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