Mercury, dimethyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas94.4 ± 0.9kJ/molReviewMartinho Simões 
Δfgas96.4 ± 4.0kJ/molReviewMartinho Simões 
Δfgas86.5 ± 2.3kJ/molReviewMartinho Simões 
Δfgas92.4 ± 3.1kJ/molReviewMartinho SimõesSelected data. Average of the values from Carson, Carson, et al., 1952 and Hartley, Pritchard, et al., 1950.
Δfgas196.8kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid61.8 ± 3.9kJ/molReviewMartinho Simões 
Δfliquid51.9 ± 2.1kJ/molReviewMartinho Simões 
Δfliquid57.8 ± 3.0kJ/molReviewMartinho SimõesSelected data. Average of the values from Carson, Carson, et al., 1952 and Hartley, Pritchard, et al., 1950.
Δfliquid59.8 ± 0.4kJ/molCC-SBCarson, Carson, et al., 1952Value corrected based on a set of ancillary data by J.A. Martinho Simões; Please also see Cox and Pilcher, 1970. The enthalpy of combustion is not reported in Carson, Carson, et al., 1952.
Quantity Value Units Method Reference Comment
Δfsolid162.2kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcsolid-1806.7kJ/molCC-SBBerthelot, 1899Please also see Berthelot, 1900.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap34.6 ± 0.8kJ/molCC-SBLong and Cattanach, 1961MS
Quantity Value Units Method Reference Comment
Δsub34.6 ± 0.8kJ/molCC-SBLong and Cattanach, 1961MS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
36.7 ± 0.1321.Baev, 2001Based on data from 275. to 367. K.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Mercury, dimethyl- (g) = CH3Hg (g) + Methane (g)

By formula: C2H6Hg (g) = CH3Hg (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr239.3 ± 6.3kJ/molKinGJackson, 1989 
Δr247. to 259.kJ/molN/ASmith and Patrick, 1983 
Δr255. ± 17.kJ/molN/AMcMillen and Golden, 1982 

Mercury, dimethyl- (l) + 2Iodine (cr) = 2Methane, iodo- (l) + Mercury diiodide (cr)

By formula: C2H6Hg (l) + 2I2 (cr) = 2CH3I (l) + HgI2 (cr)

Quantity Value Units Method Reference Comment
Δr-184.5 ± 0.8kJ/molRSCHartley, Pritchard, et al., 1950Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Mercury, dimethyl- (l) + 2Bromine (l) = 2Methane, bromo- (g) + Mercury(II) bromide (cr)

By formula: C2H6Hg (l) + 2Br2 (l) = 2CH3Br (g) + Br2Hg (cr)

Quantity Value Units Method Reference Comment
Δr-302.1 ± 2.5kJ/molRSCHartley, Pritchard, et al., 1950Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Mercury, dimethyl- (l) + Cl2Hg (cr) = 2Mercury, chloromethyl- (cr)

By formula: C2H6Hg (l) + Cl2Hg (cr) = 2CH3ClHg (cr)

Quantity Value Units Method Reference Comment
Δr-67.7 ± 2.3kJ/molRSCHartley, Pritchard, et al., 1950Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Mercury, dimethyl- (l) + Mercury(II) bromide (cr) = 2Mercury, bromomethyl- (cr)

By formula: C2H6Hg (l) + Br2Hg (cr) = 2CH3BrHg (cr)

Quantity Value Units Method Reference Comment
Δr-61.0 ± 3.1kJ/molRSCHartley, Pritchard, et al., 1950Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Mercury, dimethyl- (l) + Mercury diiodide (cr) = 2Methylmercuric iodide (cr)

By formula: C2H6Hg (l) + HgI2 (cr) = 2CH3HgI (cr)

Quantity Value Units Method Reference Comment
Δr-39.8 ± 1.6kJ/molRSCHartley, Pritchard, et al., 1950Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
Proton affinity (review)771.6kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity740.8kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
9.10 ± 0.05PIDistefano and Dibeler, 1970RDSH
9.3PECreber and Bancroft, 1980Vertical value; LLK
9.33PENugent, Wu, et al., 1976Vertical value; LLK
9.33PEFehlner, Ulman, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3+12.55CH3+Hg?PIDistefano and Dibeler, 1970RDSH
CH3Hg+10.10 ± 0.02CH3PIDistefano and Dibeler, 1970RDSH
Hg+13.05 ± 0.022CH3PIDistefano and Dibeler, 1970RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NATIONAL BUREAU OF STANDARDS, WASHINGTON D.C., USA
NIST MS number 34446

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Carson, Carson, et al., 1952
Carson, A.S.; Carson, E.M.; Wilmshurst, B., Nature, 1952, 170, 320. [all data]

Hartley, Pritchard, et al., 1950
Hartley, K.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. III.?mercury dimethyl and mercury methyl halides, Trans. Faraday Soc., 1950, 46, 1019, https://doi.org/10.1039/tf9504601019 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Berthelot, 1899
Berthelot, M., Compt. Rend., 1899, 129, 918. [all data]

Berthelot, 1900
Berthelot, M., Ann. Chim. Phys., 1900, 20, 158. [all data]

Long and Cattanach, 1961
Long, L.H.; Cattanach, J., J. Inorg. Nucl. Chem., 1961, 20, 340. [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Jackson, 1989
Jackson, R.L., Chem. Phys. Lett., 1989, 163, 315. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Distefano and Dibeler, 1970
Distefano, G.; Dibeler, V.H., Photoionization study of the dimethyl compounds of zinc, cadmium, and mercury, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 59. [all data]

Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M., Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy, Inorg. Chem., 1980, 19, 643. [all data]

Nugent, Wu, et al., 1976
Nugent, W.A.; Wu, M.M.-H.; Fehlner, T.P.; Kochi, J.K., Enhanced reactivity of exo-norbornyl derivatives. Evidence for σ-participation in the absence of steric effects, J. Chem. Soc., Chem. Commun., 1976, 456. [all data]

Fehlner, Ulman, et al., 1976
Fehlner, T.P.; Ulman, J.; Nugent, W.A.; Kochi, J.K., Effect of alkyl substituents on the first ionization potential and on 5d10 ionization in dialkylmercury compounds, Inorg. Chem., 1976, 15, 2544. [all data]


Notes

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