Cadmium, diethyl-
- Formula: C4H10Cd
- Molecular weight: 170.533
- CAS Registry Number: 592-02-9
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 32.07 ± 0.81 | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | 24.1 ± 1.7 | kcal/mol | Review | Martinho Simões | |
| ΔfH°gas | 25.17 ± 0.45 | kcal/mol | Review | Martinho Simões | Selected data |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | 13.1 ± 1.7 | kcal/mol | Review | Martinho Simões | |
| ΔfH°liquid | 14.2 ± 0.45 | kcal/mol | Review | Martinho Simões | Selected data |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔfH°solid | 21.1 ± 0.81 | kcal/mol | Review | Martinho Simões | |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -800.60 ± 0.79 | kcal/mol | CC-SB | Lautsch, Erzberger, et al., 1958 | Please also see Cox and Pilcher, 1970. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 11.0 ± 0.1 | kcal/mol | RSC | Sokolovskii and Baev, 1985 | MS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔsubH° | 11.0 ± 0.1 | kcal/mol | CC-SB | Sokolovskii and Baev, 1985 | MS |
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 11.0 ± 0.1 | 324. | Sokolovski and Baev, 1985 | Based on data from 286. to 362. K. See also Baev, 2001.; AC |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.0 | PE | Creber and Bancroft, 1980 | LLK |
| 8.2 | PE | Creber and Bancroft, 1980 | Vertical value; LLK |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Lautsch, Erzberger, et al., 1958
Lautsch, W.F.; Erzberger, P.; Tröber, A.,
Wiss. Z. Tech. Hochsch. Chem. Leuna-Merseburg, 1958, 1, 31. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Sokolovskii and Baev, 1985
Sokolovskii, A.E.; Baev, A.K.,
Vestsi Akad. Navuk BSSR, Ser. Khim. Navuk, 1985, 112.. [all data]
Sokolovski and Baev, 1985
Sokolovski, A.E.; Baev, A.K.,
Vestsi Akad. G. Emii Navuk BSSR Ser. Khim. Navuk, 1985, 1112. [all data]
Baev, 2001
Baev, A.K.,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]
Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M.,
Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy,
Inorg. Chem., 1980, 19, 643. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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