Silanol, dimethyl-

• Formula: C₂H₈OSi
• Molecular weight: 76.1698
• IUPAC Standard InChI: InChI=1S/C2H8OSi/c1-4(2)3/h3-4H,1-2H3 Copy

  
• IUPAC Standard InChIKey: LWIGVRDDANOFTD-UHFFFAOYSA-N Copy
• CAS Registry Number: 5906-76-3
• Chemical structure:
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• Other names: Dimethylsilanol
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• Information on this page:
  • Reaction thermochemistry data
  • Mass spectrum (electron ionization)
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C₂H₇OSi^- +  =

By formula: C₂H₇OSi^- + H⁺ = C₂H₈OSi

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 417

Notes

References

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]

Withnall and Andrews, 1988
Withnall, R.; Andrews, L., Matrix reactions of methylsilanes and oxygen atoms, J. Phys. Chem., 1988, 92, 3, 594, https://doi.org/10.1021/j100314a006 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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