Silanol, dimethyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C2H7OSi- + Hydrogen cation = Silanol, dimethyl-

By formula: C2H7OSi- + H+ = C2H8OSi

Quantity Value Units Method Reference Comment
Δr358.9 ± 4.1kcal/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Δr352.5 ± 4.0kcal/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

OH stretch 3717.1 Ar IR Withnall and Andrews, 1988
SiH stretch 2111.0 Ar IR Withnall and Andrews, 1988
925 vs Ar IR Withnall and Andrews, 1988
819.4 Ar IR Withnall and Andrews, 1988
808.8 Ar IR Withnall and Andrews, 1988
HSiO bend 764.5 Ar IR Withnall and Andrews, 1988
757.2 Ar IR Withnall and Andrews, 1988
SiOH bend 711.0 Ar IR Withnall and Andrews, 1988
707.3 Ar IR Withnall and Andrews, 1988
616.2 Ar IR Withnall and Andrews, 1988
CSiC bend 283 Ar IR Withnall and Andrews, 1988

Additional references: Jacox, 1994, page 417

Notes

vsVery strong

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]

Withnall and Andrews, 1988
Withnall, R.; Andrews, L., Matrix reactions of methylsilanes and oxygen atoms, J. Phys. Chem., 1988, 92, 3, 594, https://doi.org/10.1021/j100314a006 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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