(Z)-1,2-Diiodoethylene
- Formula: C2H2I2
- Molecular weight: 279.8462
- IUPAC Standard InChIKey: CVOGMKGEVNGRSK-UPHRSURJSA-N
- CAS Registry Number: 590-26-1
- Chemical structure:
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 207.4 ± 0.84 | kJ/mol | Eqk | Furuyama, Golden, et al., 1968 | Reanalyzed by Cox and Pilcher, 1970, Original value = 206. ± 0.4 kJ/mol |
Phase change data
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 260. | K | N/A | Andrews and Keefer, 1951 | Uncertainty assigned by TRC = 2. K; may be eutectic of 20% trans- and 80% cis-isomers; TRC |
Reduced pressure boiling point
Tboil (K) | Pressure (bar) | Reference | Comment |
---|---|---|---|
345.7 | 0.021 | Weast and Grasselli, 1989 | BS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
46.5 | 317. | A | Stephenson and Malanowski, 1987 | Based on data from 302. to 425. K. See also Dykyj, 1970.; AC |
47.3 | 317. | N/A | Noyes, Noyes, et al., 1950 | Based on data from 302. to 424. K.; AC |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.6 | PE | Wittel, Bock, et al., 1974 | LLK |
8.94 | PE | Wittel, Bock, et al., 1974 | Vertical value; LLK |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Furuyama, Golden, et al., 1968
Furuyama, S.; Golden, D.M.; Benson, S.W.,
The thermochemistry of the gas-phase equilibria trans-1,2-diiodoethylene = acetylene + I2 and trans-1,2-diiodoethylene = cis-1,2-diiodoethylene,
J. Phys. Chem., 1968, 72, 3204-3208. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Andrews and Keefer, 1951
Andrews, L.J.; Keefer, R.M.,
The Argentation of Organic Iodides,
J. Am. Chem. Soc., 1951, 73, 5733-5736. [all data]
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Dykyj, 1970
Dykyj, J.,
Petrochemica, 1970, 10, 2, 51. [all data]
Noyes, Noyes, et al., 1950
Noyes, Richard M.; Noyes, Winninette A.; Steinmetz, Hyman,
Vapor Pressures of cis and trans Disubstituted Ethylenes,
J. Am. Chem. Soc., 1950, 72, 1, 33-34, https://doi.org/10.1021/ja01157a008
. [all data]
Wittel, Bock, et al., 1974
Wittel, K.; Bock, H.; Manne, R.,
Photoelectron spectra of iodo ethylenes. A simple method to incorporate spin orbit coupling in molecular orbital models,
Tetrahedron, 1974, 30, 651. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔfH°gas Enthalpy of formation of gas at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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