Hexane, 3-methyl-
- Formula: C7H16
- Molecular weight: 100.2019
- IUPAC Standard InChI: InChI=1S/C7H16/c1-4-6-7(3)5-2/h7H,4-6H2,1-3H3
- IUPAC Standard InChIKey: VLJXXKKOSFGPHI-UHFFFAOYSA-N
- CAS Registry Number: 589-34-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: 2-Ethylpentane; 3-Methylhexane
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Normal boiling point
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
| Tboil (K) | Reference | Comment |
|---|---|---|
| 364.2 | Aldrich Chemical Company Inc., 1990 | BS; Data excluded from overall average |
| 365. | Majer and Svoboda, 1985 | |
| 364.7 | Petrov, Sergienko, et al., 1958 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365. | Desty and Whyman, 1957 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 365.05 | Roebuck and Evering, 1953 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 365.05 | Heller, 1952 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365.03 | Boord, Henne, et al., 1949 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 364.75 | Buck, Elsner, et al., 1949 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 364.75 | Denyer, Fidler, et al., 1949 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 365.0000 | Forziati and Rossini, 1949 | Uncertainty assigned by TRC = 0.2 K; TRC |
| 365.15 | Lecat, 1949 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365. | Rossini, Mair, et al., 1949 | Uncertainty assigned by TRC = 0.2 K; TRC |
| 365.2 | Rossini, 1948 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365.04 | Boord, Greenlee, et al., 1947 | Uncertainty assigned by TRC = 0.2 K; TRC |
| 365.0 | Brescia, 1947 | Uncertainty assigned by TRC = 0.2 K; TRC |
| 365. | Fenske, Braun, et al., 1947 | Uncertainty assigned by TRC = 0.15 K; TRC |
| 363.65 | Shikheev, 1946 | Uncertainty assigned by TRC = 3. K; TRC; Data excluded from overall average |
| 365.3 | Grummitt, Sensel, et al., 1945 | Uncertainty assigned by TRC = 1.5 K; TRC |
| 365.15 | Appleby, Dobratz, et al., 1944 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365.1 | Forziati, Willingham, et al., 1944 | Uncertainty assigned by TRC = 0.06 K; TRC |
| 364.75 | Anonymous, 1943 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 365.2 | Rossini, 1943 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365.11 | Davies and Gilbert, 1941 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 365.15 | Henne, Chanan, et al., 1941 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 364.95 | Koch and Hilberath, 1941 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365.11 | Glasgow, 1940 | Uncertainty assigned by TRC = 0.2 K; TRC |
| 364.75 | Beltz, 1939 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365.03 | Wojciechowski, 1939 | Uncertainty assigned by TRC = 0.2 K; TRC |
| 364.95 | Hoog, Smittenberg, et al., 1937 | Uncertainty assigned by TRC = 0.6 K; from Egloff, Vol. 1, 1939; TRC |
| 365.15 | Leslie and White, 1935 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 365.15 | Rossini, 1935 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 362.5 | Soday and Boord, 1933 | Uncertainty assigned by TRC = 2. K; boiling point given corresponds to that for 2,3-dimethylpentane; TRC; Data excluded from overall average |
| 364.95 | McKee and Szayna, 1930 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 364.95 | Edgar, Calingaert, et al., 1929 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 364.95 | Edgar and Calingaert, 1929 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 364.95 | Timmermans, 1927 | Uncertainty assigned by TRC = 0.5 K; source of data not clear; TRC |
| 364.95 | De Graef, 1925 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 363.65 | Timmermans, 1921 | Uncertainty assigned by TRC = 0.7 K; TRC; Data excluded from overall average |
References
Go To: Top, Normal boiling point, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
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Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
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Petrov, A.A.; Sergienko, S.R.; Tsedlina, A.L.; Teterina, M.P.; Kislinskii, A.N.; Gal'pern, G.D.,
Isomerization of Saturated Hydrocarbons Communication 1. Isomerization of C6-C8 Parafins,
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Roebuck and Evering, 1953
Roebuck, A.K.; Evering, B.L.,
Sulfuric Acid Isomerization of Methylalkanes, Dimethylalkanes, and Dimethylcyclohexanes,
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Heller, 1952
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The Racemization of d(+)-3-Methylhexane,
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Boord, Henne, et al., 1949
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The Grignard Reagent in hydrocarbon synthesis,
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Buck, Elsner, et al., 1949
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Hydrocarbon synthesis.,
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Lecat, 1949
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Homofunctional azeotropes of hydrocarbons,
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Pure compounds from petroleum purification and purity of hydrocarbons,
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The Critical Temperature,
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Raman Spectra of Hydrocarbons,
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Methylpropylethynyl- and Methylpropylvinylcarbinols and Hydrocarbons Obtained from Them,
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Grummitt, Sensel, et al., 1945
Grummitt, O.; Sensel, E.E.; Smith, W.R.; Burk, R.E.; Lankelma, H.P.,
The Action of Aluminum Bromide on Paraffin Hydrocarbons I. n-Hexane and n-Heptane,
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Vapor Phase Dehydration of 1-Heptanol ofer Activated Alumina,
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Forziati, Willingham, et al., 1944
Forziati, A.F.; Willingham, C.B.; Mair, B.J.; Rossini, F.D.,
Hydrocarbons in the Gasolene Fraction of Seven Representative Crudes, Including All the Distillates to 102 deg. C and the Aromatics to 160 C,
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Anonymous, 1943
Anonymous, R.,
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Rossini, 1943
Rossini, F.D.,
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Davies and Gilbert, 1941
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Olefins and Diolefins from Allylic Chlorides,
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Uber unterhalb 100C siedenden kohlenwassestoffe des synthetischen benzins aus kohlenoxyd und wasserstoff (kogasin),
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Isolation of 3-methylhexane, trans-1,2-dimethylcyclopentane, and trans-1,3- dimethylcyclopentane from petroleum,
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Notes
Go To: Top, Normal boiling point, References
- Symbols used in this document:
Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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