CS2+

• Formula: CS₂⁺
• Molecular weight: 76.140
• CAS Registry Number: 56283-12-6
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Options:
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CS₂⁺ +  = (CS₂⁺ • )

By formula: CS₂⁺ + CS₂ = (CS₂⁺ • CS₂)

(CS₂⁺ • 2) +  = (CS₂⁺ • 3)

By formula: (CS₂⁺ • 2CS₂) + CS₂ = (CS₂⁺ • 3CS₂)

(CS₂⁺ • ) +  = (CS₂⁺ • 2)

By formula: (CS₂⁺ • CS₂) + CS₂ = (CS₂⁺ • 2CS₂)

(CS₂⁺ • 3) +  = (CS₂⁺ • 4)

By formula: (CS₂⁺ • 3CS₂) + CS₂ = (CS₂⁺ • 4CS₂)

CS₂⁺ +  = (CS₂⁺ • )

By formula: CS₂⁺ + COS = (CS₂⁺ • COS)

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CS₂⁺ +  = (CS₂⁺ • )

By formula: CS₂⁺ + COS = (CS₂⁺ • COS)

CS₂⁺ +  = (CS₂⁺ • )

By formula: CS₂⁺ + CS₂ = (CS₂⁺ • CS₂)

(CS₂⁺ • ) +  = (CS₂⁺ • 2)

By formula: (CS₂⁺ • CS₂) + CS₂ = (CS₂⁺ • 2CS₂)

(CS₂⁺ • 2) +  = (CS₂⁺ • 3)

By formula: (CS₂⁺ • 2CS₂) + CS₂ = (CS₂⁺ • 3CS₂)

(CS₂⁺ • 3) +  = (CS₂⁺ • 4)

By formula: (CS₂⁺ • 3CS₂) + CS₂ = (CS₂⁺ • 4CS₂)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C

State:   B

State:   A

State:   X

Additional references: Jacox, 1994, page 79; Jacox, 1998, page 186; Jacox, 2003, page 125; Smith, 1969; Eland, Devoret, et al., 1976; Maier and Thommen, 1980; Dunbar and Turner, 1981; Ibuki and Sugita, 1984

Notes

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Frontier-Controlled Structures of the Gas-Phase A+-(CS2)n Clusters ,A+- = S2+, CS2+, S2-, and CS2-, J. Phys. Chem., 1994, 98, 7, 1802, https://doi.org/10.1021/j100058a014 . [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry, J. Chem. Phys., 1977, 66, 10, 4527, https://doi.org/10.1063/1.433706 . [all data]

Ono, Linn, et al., 1980
Ono, Y.; Linn, S.H.; Prest, H.F.; Gress, M.E.; Ng, C.Y., Molecular beam photoionization study of carbon disulfide, carbon disulfide dimer and clusters, J. Chem. Phys., 1980, 73, 2523. [all data]

Ono, Osuch, et al., 1981
Ono, Y.; Osuch, E.A.; Ng, C.Y., Molecular beam photoionization study of OCS, (OCS)₂, (OCS)₃, and OCS.CS₂, J. Chem. Phys., 1981, 74, 1645. [all data]

Frey, Gotchev, et al., 1978
Frey, R.; Gotchev, B.; Peatman, W.B.; Pollak, H.; Schlag, E.W., Photoionization resonance study of the X(²π), A(²π), B(²Σ⁺) and C(²Σ⁺) states of CS₂⁺ and CO_S⁺, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 137. [all data]

Danis, Wyttenbach, et al., 1988
Danis, P.O.; Wyttenbach, T.; Maier, J.P., Two-photon absorption spectroscopy of mass-selected ions: N2O+ and CS+2, J. Chem. Phys., 1988, 88, 6, 3451, https://doi.org/10.1063/1.453893 . [all data]

Evard, Wyttenbach, et al., 1989
Evard, D.D.; Wyttenbach, T.; Maier, J.P., Two-photon absorption spectroscopy of ion beams: carbon disulfide(1+) ~C2.SIGMA.g+ state characterization, J. Phys. Chem., 1989, 93, 9, 3522, https://doi.org/10.1021/j100346a032 . [all data]

Potts and Fattahallah, 1980
Potts, A.W.; Fattahallah, G.H., High-resolution ultraviolet photoelectron spectroscopy of CO₂, COS and CS₂, J. Phys. B:, 1980, 13, 2545. [all data]

Kovac, 1983
Kovac, B., The He i photoelectron spectra of CO2, CS2, and OCS: Vibronic coupling, J. Chem. Phys., 1983, 78, 4, 1684, https://doi.org/10.1063/1.444967 . [all data]

Wang, Reutt, et al., 1988
Wang, L.; Reutt, J.E.; Lee, Y.T.; Shirley, D.A., High resolution UV photoelectron spectroscopy of CO₂, COS, and CS₂ using supersonic molecular beams, J. Electron Spectrosc. Relat. Phenom., 1988, 47, 167. [all data]

Baltzer, Wannberg, et al., 1996
Baltzer, P.; Wannberg, B.; Lundqvist, M.; Karlsson, L.; Holland, D.M.P.; MacDonald, M.A.; Hayes, M.A.; Tomasello, P.; von Niessen, W., An experimental and theoretical study of the valence shell photoelectron spectrum of carbon disulphide, Chem. Phys., 1996, 202, 1, 185, https://doi.org/10.1016/0301-0104(95)00303-7 . [all data]

Zhuang, Zhang, et al., 2006
Zhuang, X.; Zhang, L.; Wang, J.; Ma, Y.; Yu, S.; Liu, S.; Ma, X., Study on the Photodissociation Spectra of CS, J. Phys. Chem. A, 2006, 110, 19, 6256, https://doi.org/10.1021/jp060533f . [all data]

Callomon, 1958
Callomon, J.H., Electronic Emission Spectra of the Carbon Disulphide Ion, CSFormula, Proc. Roy. Soc. (London) A244, 1958, 244, 1237, 220, https://doi.org/10.1098/rspa.1958.0038 . [all data]

Bondybey and English, 1980
Bondybey, V.E.; English, J.H., Spectroscopy and relaxation of CS2+ in solid Ne, J. Chem. Phys., 1980, 73, 7, 3098, https://doi.org/10.1063/1.440544 . [all data]

Balfour, 1976
Balfour, W.J., The and band systems of the CS, Can. J. Phys., 1976, 54, 19, 1969, https://doi.org/10.1139/p76-235 . [all data]

Venkitachalam, 1999
Venkitachalam, T.V., A tentative multiphoton ionization of CS2 molecule: Spectroscopy of Ã2πu state of CS 2 + ion, Pramana, 1999, 52, 2, 177, https://doi.org/10.1007/BF02831493 . [all data]

He and Clouthier, 2006
He, S.-G.; Clouthier, D.J., The molecular structure and a Renner-Teller analysis of the ground and first excited electronic states of the jet-cooled CS[sub 2][sup +] molecular ion, J. Chem. Phys., 2006, 12, 8, 084312, https://doi.org/10.1063/1.2172612 . [all data]

Bondybey, English, et al., 1979
Bondybey, V.E.; English, J.H.; Miller, T.A., Laser induced fluorescence spectrum of matrix isolated CS+2, J. Chem. Phys., 1979, 70, 4, 1621, https://doi.org/10.1063/1.437702 . [all data]

Cheng, Lo, et al., 1995
Cheng, B.-M.; Lo, W.-J.; Hung, W.-C., Photoionization threshold of CS2 in solid neon, Chem. Phys. Lett., 1995, 236, 3, 355, https://doi.org/10.1016/0009-2614(95)00224-R . [all data]

Lorenz and Bondybey, 2000
Lorenz, M.; Bondybey, V.E., Deposition of mass-selected ions in neon matrices: CS[sub 2][sup +] and C[sub 6]F[sub 6][sup +], Low Temp. Phys., 2000, 26, 9, 778, https://doi.org/10.1063/1.1312407 . [all data]

Liu, Hochlaf, et al., 2001
Liu, J.; Hochlaf, M.; Chambaud, G.; Rosmus, P.; Ng, C.Y., High Resolution Pulsed Field Ionization-Photoelectron Bands for CS, J. Phys. Chem. A, 2001, 105, 11, 2183, https://doi.org/10.1021/jp001998n . [all data]

Zen and Lee, 1995
Zen, C.-C.; Lee, Y.-P., Laser-induced fluorescence of the A2πu-X2πg transition of CS2+ in solid Ne. Reanalysis of vibronic spectra, Chem. Phys. Lett., 1995, 244, 1-2, 177, https://doi.org/10.1016/0009-2614(95)00919-U . [all data]

Fischer, Lochschmidt, et al., 1993
Fischer, I.; Lochschmidt, A.; Strobel, A.; Niedner-Schatteburg, G.; Muller-Dethlefs, K.; Bondybey, V.E., The non-resonant two-photon zero kinetic energy photoelectron spectrum of CS₂, Chem. Phys. Lett., 1993, 202, 542. [all data]

Huang, Cheung, et al., 1997
Huang, J.-C.; Cheung, Y.-S.; Evans, M.; Liao, C.-X.; Ng, C.Y.; Hsu, C.-W.; Heimann, P.; Lefebvre-Brion, H.; Cossart-Magos, C., A high-resolution vacuum ultraviolet photoionization, photoelectron, and pulsed field ionization study of CS2 near the CS[sub 2][sup +](X 2Π3/2,1/2) thresholds, J. Chem. Phys., 1997, 106, 3, 864, https://doi.org/10.1063/1.473967 . [all data]

Halasinski, Godbout, et al., 1996
Halasinski, T.M.; Godbout, J.T.; Allison, J.; Leroi, G.E., Matrix Isolation and Cold Diffusion of Mass-Selected CS, J. Phys. Chem., 1996, 100, 36, 14865, https://doi.org/10.1021/jp960862f . [all data]

Zhou and Andrews, 2000
Zhou, M.; Andrews, L., Infrared spectra of the CS[sub 2][sup -], CS[sub 2][sup +], and C[sub 2]S[sub 4][sup +] molecular ions in solid neon and argon, J. Chem. Phys., 2000, 112, 15, 6576, https://doi.org/10.1063/1.481230 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Smith, 1969
Smith, W.H., Radiative Lifetimes and Total Transition Probabilities for Some Polyatomic Species, J. Chem. Phys., 1969, 51, 8, 3410, https://doi.org/10.1063/1.1672528 . [all data]

Eland, Devoret, et al., 1976
Eland, J.H.D.; Devoret, M.; Leach, S., Quantum yields and lifetimes of molecular ion fluorescence, Chem. Phys. Lett., 1976, 43, 1, 97, https://doi.org/10.1016/0009-2614(76)80765-8 . [all data]

Maier and Thommen, 1980
Maier, J.P.; Thommen, F., Fluorescence quantum yields and cascade-free lifetimes of state selected CO+2, COS+, CS+2 and N2O+ determined by photoelectron---photon coincidence spectroscopy, Chem. Phys., 1980, 51, 3, 319, https://doi.org/10.1016/0301-0104(80)80106-6 . [all data]

Dunbar and Turner, 1981
Dunbar, R.C.; Turner, D.W., Wavelength-resolved fluorescence lifetimes of gas-phase ions: CO2+ and CS2+, Chem. Phys., 1981, 57, 3, 377, https://doi.org/10.1016/0301-0104(81)80216-9 . [all data]

Ibuki and Sugita, 1984
Ibuki, T.; Sugita, N., Lifetimes of N2O+(A), CS+2(A), and CS+2(B) states produced by pulsed EUV photons, J. Chem. Phys., 1984, 80, 10, 4625, https://doi.org/10.1063/1.446547 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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