Molybdenum, tetracarbonylbis(η5-2,4-cyclopentadien-1-yl)di-, (mo-mo)
- Formula: C14H10Mo2O4
- Molecular weight: 434.15
- CAS Registry Number: 56200-27-2
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C14H10Mo2O4 (solution) + 2 (solution) = C16H10Mo2O6 (solution)
By formula: C14H10Mo2O4 (solution) + 2CO (solution) = C16H10Mo2O6 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -40.30 ± 0.33 | kcal/mol | RSC | Nolan, López de la Vega, et al., 1986 | solvent: Toluene; The enthalpy of solution of [Mo(Cp)(CO)2]2(cr) was measured as 3.80 ± 0.1 kcal/mol Nolan, López de la Vega, et al., 1986 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.1 | PE | Morris-Sherwood, Powell, et al., 1984 | |
| 7.35 | PE | Morris-Sherwood, Powell, et al., 1984 | Vertical value |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D.,
Inorg. Chem., 1986, 25, 4446. [all data]
Morris-Sherwood, Powell, et al., 1984
Morris-Sherwood, B.J.; Powell, C.B.; Hall, M.B.,
Photoelectron spectra and molecular orbital calculations on bis(cyclopentadienyldicarbonylchromium, -molybdenum, and -tungsten): Nature of the bonding of linear semibridging carbonyls,
J. Am. Chem. Soc., 1984, 106, 5079. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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