Mo(CO)3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CO stretch 2000 ± 10 gas IR PE Ganske and Rosenfeld, 1989
Bengali, Casey, et al., 1992
2 MoCO bend 660 ± 10 gas PE Bengali, Casey, et al., 1992
4 CMoC bend 100 ± 20 gas PE Bengali, Casey, et al., 1992
e CO stretch 1891 gas IR Ganske and Rosenfeld, 1989
Ishikawa, Brown, et al., 1990
CO stretch 1886.1 Ne IR Andrews, Zhou, et al., 2003
CO stretch 1869 Ar IR Perutz and Turner, 1975

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ganske and Rosenfeld, 1989
Ganske, J.A.; Rosenfeld, R.N., Photochemistry of molybdenum hexacarbonyl in the gas phase, J. Phys. Chem., 1989, 93, 5, 1959, https://doi.org/10.1021/j100342a051 . [all data]

Bengali, Casey, et al., 1992
Bengali, A.A.; Casey, S.M.; Cheng, C.-L.; Dick, J.P.; Fenn, T.; Villaalta, P.W.; Leopold, D.G., Negative Ion Photoelectron Spectroscopy of Coordinatively Unsaturated Group VI Metal Carbonyls: Cr(CO)3, Mo(CO)3, and W(CO)3, J. Am. Chem. Soc., 1992, 114, 13, 5257, https://doi.org/10.1021/ja00039a043 . [all data]

Ishikawa, Brown, et al., 1990
Ishikawa, Y.; Brown, C.E.; Hackett, P.A.; Rayner, D.M., Excimer laser photolysis of Group 6 metal carbonyls in the gas phase, J. Phys. Chem., 1990, 94, 6, 2404, https://doi.org/10.1021/j100369a040 . [all data]

Andrews, Zhou, et al., 2003
Andrews, L.; Zhou, M.; Gutsev, G.L., Reactions of Laser-Ablated Mo and W Atoms, Cations, and Electrons with CO in Excess Neon: Infrared Spectra and Density Functional Calculations on Neutral and Charged Unsaturated Metal Carbonyls, J. Phys. Chem. A, 2003, 107, 7, 990, https://doi.org/10.1021/jp026978v . [all data]

Perutz and Turner, 1975
Perutz, R.N.; Turner, J.J., Photochemistry of the Group 6 hexacarbonyls in low-temperature matrixes. IV. Tetracarbonylmolybdenum and tricarbonylmolybdenum, J. Am. Chem. Soc., 1975, 97, 17, 4800, https://doi.org/10.1021/ja00850a002 . [all data]

Notes

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