Phosphenothious fluoride

• Formula: FPS
• Molecular weight: 82.037
• CAS Registry Number: 55753-39-4
• Information on this page:
  • Gas phase thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 104; Jacox, 2003, page 142

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Beckers, Bogey, et al., 2000
Beckers, H.; Bogey, M.; Breidung, J.; Burger, H.; Drean, P.; Paplewski, P.; Thiel, W.; Walters, A., FP=S in the gas-phase: Detection by rotationally resolved infrared and millimetre-wave spectra assisted by ab-initio calculations, Phys. Chem. Chem. Phys., 2000, 2, 11, 2467, https://doi.org/10.1039/b002625p . [all data]

Schnockel and Schunck, 1987
Schnockel, H.; Schunck, S., Matrix-IR-Untersuchungen von molekularem SPF, Z. Anorg. Allg. Chem., 1987, 552, 9, 163, https://doi.org/10.1002/zaac.19875520918 . [all data]

Beckers, Bogey, et al., 2001
Beckers, H.; Bogey, M.; Breidung, J.; Burger, H.; Demaison, J.; Drean, P.; Paplewski, P.; Thiel, W.; Walters, A., Millimeter-Wave Spectroscopy, High-Resolution Infrared Spectrum, ab Initio Calculations, and Molecular Geometry of FPS, J. Mol. Spectrosc., 2001, 210, 2, 213, https://doi.org/10.1006/jmsp.2001.8462 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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