Dimethylzinc

• Formula: C₂H₆Zn
• Molecular weight: 95.45
• IUPAC Standard InChI: InChI=1S/2CH3.Zn/h2*1H3; Copy

  
• IUPAC Standard InChIKey: AXAZMDOAUQTMOW-UHFFFAOYSA-N Copy
• CAS Registry Number: 544-97-8
• Chemical structure:
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 (l) + ( • 100) (solution) = 2 (g) + ( • 100) (solution)

By formula: C₂H₆Zn (l) + (H₂O₄S • 100H₂O) (solution) = 2CH₄ (g) + (O₄SZn • 100H₂O) (solution)

 (g) =  (g) +  (g)

By formula: C₂H₆Zn (g) = CH₃Zn (g) + CH₄ (g)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Carson, Hartley, et al., 1949
Carson, A.S.; Hartley, K.; Skinner, H.A., Thermochemistry of metal alkyls. Part II.?The bond dissociation energies of some Zn?C and Cd?C bonds, and of Et?I., Trans. Faraday Soc., 1949, 45, 1159, https://doi.org/10.1039/tf9494501159 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Jackson, 1989
Jackson, R.L., Chem. Phys. Lett., 1989, 163, 315. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Distefano and Dibeler, 1970
Distefano, G.; Dibeler, V.H., Photoionization study of the dimethyl compounds of zinc, cadmium, and mercury, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 59. [all data]

Winters and Kiser, 1967
Winters, R.E.; Kiser, R.W., Ionization and fragmentation of dimethylzinc, trimethylaluminum, and trimethylantimony, J. Organometal. Chem., 1967, 10, 7. [all data]

Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M., Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy, Inorg. Chem., 1980, 19, 643. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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