Pentamethyl tantalum


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C5H15Ta (l) + 2.5Water (l) = 0.5O5Ta2 (cr) + 5Methane (g)

By formula: C5H15Ta (l) + 2.5H2O (l) = 0.5O5Ta2 (cr) + 5CH4 (g)

Quantity Value Units Method Reference Comment
Δr-853. ± 26.kJ/molRSCAdedeji, Connor J.A., et al., 1976 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.2PEGalyer, Wilkinson, et al., 1975LLK
8.83 ± 0.02PEGreen, Lloyd, et al., 1978Vertical value; LLK
8.7PEGalyer, Wilkinson, et al., 1975Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Adedeji, Connor J.A., et al., 1976
Adedeji, F.A.; Connor J.A.; Skinner, H.A.; Galyer, L.; Wilkinson, G., J. Chem. Soc., Chem. Commun., 1976, 159.. [all data]

Galyer, Wilkinson, et al., 1975
Galyer, L.; Wilkinson, G.; Lloyd, D.R., The photoelectron spectra of hexamethyltungsten and pentamethyltantalum, J. Chem. Soc., Chem. Commun., 1975, 497. [all data]

Green, Lloyd, et al., 1978
Green, J.C.; Lloyd, D.R.; Galyer, L.; Mertis, K.; Wilkinson, G., Photoelectron spectra of some transition metal alkyls and oxoalkyls, J. Chem. Soc. Dalton Trans., 1978, 10, 1403. [all data]


Notes

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