Iridium, (2,4-pentanedionato-o,o'-)-bisη²-ethene

• Formula: C₉H₁₅IrO₂
• Molecular weight: 347.431
• CAS Registry Number: 52654-27-0
• Information on this page:
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Options:
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C₉H₁₅IrO₂ (cr) + 2 (g) = C₇H₇IrO₄ (cr) + 2 (g)

By formula: C₉H₁₅IrO₂ (cr) + 2CO (g) = C₇H₇IrO₄ (cr) + 2C₂H₄ (g)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jesse, Ernsting, et al., 1978
Jesse, A.C.; Ernsting, J.M.; Stufkens, D.J.; Vrieze, K., Thermochim. Acta, 1978, 25, 69. [all data]

Jesse, Ernsting, et al., 1978, 2
Jesse, A.C.; Ernsting, J.M.; Stufkens, D.J.; Vrieze, K., Vapour pressure measurements on (acac)M(substituted olefin)2 and (acac)M(CO)2 (M = Rh(I), Ir(I)), Thermochimica Acta, 1978, 25, 1, 69-75, https://doi.org/10.1016/0040-6031(78)80041-0 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Jesse, Baks, et al., 1978
Jesse, A.C.; Baks, A.; Stufkens, D.J.; Vrieze, K., Inorg. Chim. Acta, 1978, 29, 177. [all data]

Van Dam, Terpstra, et al., 1980
Van Dam, H.; Terpstra, A.; Stufkens, D.J.; Oskam, A., UV photoelectron spectroscopic studies of the metal-olefin bond. 2. Bonding in (β-diketonato)rhodium(I) and -iridium(I) carbonyl and olefin complexes, Inorg. Chem., 1980, 19, 3448. [all data]

Notes

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• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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