Iridium, (2,4-pentanedionato-o,o'-)-bisη2-ethene
- Formula: C9H15IrO2
- Molecular weight: 347.431
- CAS Registry Number: 52654-27-0
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C9H15IrO2 (cr) + 2 (g) = C7H7IrO4 (cr) + 2 (g)
By formula: C9H15IrO2 (cr) + 2CO (g) = C7H7IrO4 (cr) + 2C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -74.1 ± 4.6 | kJ/mol | DSC | Jesse, Baks, et al., 1978 |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.1 | PE | Van Dam, Terpstra, et al., 1980 | |
7.36 | PE | Van Dam, Terpstra, et al., 1980 | Vertical value |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Jesse, Baks, et al., 1978
Jesse, A.C.; Baks, A.; Stufkens, D.J.; Vrieze, K.,
Inorg. Chim. Acta, 1978, 29, 177. [all data]
Van Dam, Terpstra, et al., 1980
Van Dam, H.; Terpstra, A.; Stufkens, D.J.; Oskam, A.,
UV photoelectron spectroscopic studies of the metal-olefin bond. 2. Bonding in (β-diketonato)rhodium(I) and -iridium(I) carbonyl and olefin complexes,
Inorg. Chem., 1980, 19, 3448. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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