CH2=CHCl+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 70630 ± 100 gas Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974
Locht, Leyh, et al., 1997

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 50830 ± 320 gas Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 43410 ± 320 gas Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 28640 ± 500 gas Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 25250 ± 320 gas Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13385 ± 10 gas Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974
Locht, Leyh, et al., 1997
Lee and Kim, 2006
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 CH stretch 3122 ± 80 gas TPI Lee and Kim, 2006
3 CH stretch 2883 gas TPI Lee and Kim, 2006
4 1546 gas TPI Lee and Kim, 2006
6 1172 gas UB Mines and Thompson, 1973
Wittel and Bock, 1974
Locht, Leyh, et al., 1997
Lee and Kim, 2006
8 HCCl bend 524 gas UB Mines and Thompson, 1973
Wittel and Bock, 1974
Locht, Leyh, et al., 1997
Lee and Kim, 2006
9 259 gas UB Locht, Leyh, et al., 1997
Lee and Kim, 2006
a 12 558 gas UB Lee and Kim, 2006

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' C=C stretch 1320 ± 70 gas PE TPE Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974
Locht, Leyh, et al., 1997
1130 ± 60 gas TPE Locht, Leyh, et al., 1997
CCl stretch 820 ± 20 gas PE TPE Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974
Locht, Leyh, et al., 1997
HCCl bend 430 ± 40 gas PE TPE Lake and Thompson, 1970
Mines and Thompson, 1973
Wittel and Bock, 1974
Locht, Leyh, et al., 1997

Additional references: Jacox, 1994, page 319

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lake and Thompson, 1970
Lake, R.F.; Thompson, H., Photoelectron spectra of halogenated ethylenes, Proc. Roy. Soc. (London), 1970, A315, 323. [all data]

Mines and Thompson, 1973
Mines, G.W.; Thompson, H.W., Photoelectron spectra of vinyl and allyl halides, Spectrochim. Acta Part A, 1973, 29, 1377. [all data]

Wittel and Bock, 1974
Wittel, K.; Bock, H., Photoelektronenspekten und molekuleigenschaften. XXVII. Chlor- und bromathylene- beispiele fur anderungen in π- und σ-Systemen, Chem. Ber., 1974, 107, 317. [all data]

Locht, Leyh, et al., 1997
Locht, R.; Leyh, B.; Hottmann, K.; Baumgartel, H., The He(I), threshold photoelectron and constant ion state spectroscopy of vinylchloride (C2H3Cl), Chem. Phys., 1997, 220, 1-2, 217, https://doi.org/10.1016/S0301-0104(97)00128-6 . [all data]

Lee and Kim, 2006
Lee, M.; Kim, M.S., Mass-Analyzed Threshold Ionization Study of Vinyl Chloride Cation in the First Excited Electronic State Using Vacuum Ultraviolet Radiation in the 107-102.8 nm Range, J. Phys. Chem. A, 2006, 110, 30, 9377, https://doi.org/10.1021/jp062456u . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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