tert-Butyl hypochlorite
- Formula: C4H9ClO
- Molecular weight: 108.567
- IUPAC Standard InChI: InChI=1S/C4H9ClO/c1-4(2,3)6-5/h1-3H3
- IUPAC Standard InChIKey: IXZDIALLLMRYOU-UHFFFAOYSA-N
- CAS Registry Number: 507-40-4
- Chemical structure:
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Robert L. Brown and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tboil | 350.7 | K | N/A | Weast and Grasselli, 1989 | |
| Tboil | 350. to 351. | K | N/A | Frinton Laboratories Inc., 1986 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.91 ± 0.02 | PE | Colbourne, Frost, et al., 1981 | Vertical value; LLK |
UV/Visible spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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| Source | Anbar and Dostrovsky, 1954 |
|---|---|
| Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
| Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
| Source reference | RAS UV No. 12067 |
| Instrument | Beckman DU |
| Boiling point | 77.5 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Frinton Laboratories Inc., 1986
Frinton Laboratories Inc.,
Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]
Colbourne, Frost, et al., 1981
Colbourne, D.; Frost, D.C.; McDowell, C.A.; Westwood, N.P.C.,
The He(I) photoelectron spectra of the alkyl hypochlorites, ROCl (R = Me, Et and t-Bu),
J. Electron Spectrosc. Relat. Phenom., 1981, 23, 109. [all data]
Anbar and Dostrovsky, 1954
Anbar, M.; Dostrovsky, I.,
J. Chem. Soc., 1954, 1105. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, UV/Visible spectrum, References
- Symbols used in this document:
Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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