dimethylcadmium

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas29.4 ± 2.9kcal/molReviewMartinho Simões 
Δfgas24.4 ± 1.0kcal/molReviewMartinho Simões 
Δfgas25.05 ± 0.31kcal/molReviewMartinho SimõesSelected data.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H6Cd (g) = CH3Cd (g) + Methane (g)

By formula: C2H6Cd (g) = CH3Cd (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr56.0 ± 1.5kcal/molKinGJackson, 1989 
Δr58.1 to 60.9kcal/molN/ASmith and Patrick, 1983 
Δr60.0 ± 4.0kcal/molN/AMcMillen and Golden, 1982 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.56 ± 0.02PIDistefano and Dibeler, 1970RDSH
8.8PECreber and Bancroft, 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3Cd+9.69 ± 0.02CH3PIDistefano and Dibeler, 1970RDSH
Cd+12.10 ± 0.022CH3PIDistefano and Dibeler, 1970RDSH

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Jackson, 1989
Jackson, R.L., Chem. Phys. Lett., 1989, 163, 315. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Distefano and Dibeler, 1970
Distefano, G.; Dibeler, V.H., Photoionization study of the dimethyl compounds of zinc, cadmium, and mercury, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 59. [all data]

Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M., Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy, Inorg. Chem., 1980, 19, 643. [all data]


Notes

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