Diazene, dimethyl-

• Formula: C₂H₆N₂
• Molecular weight: 58.0824
• IUPAC Standard InChI: InChI=1S/C2H6N2/c1-3-4-2/h1-2H3 Copy

  
• IUPAC Standard InChIKey: JCCAVOLDXDEODY-UHFFFAOYSA-N Copy
• CAS Registry Number: 503-28-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Stereoisomers:
  • (E)-CH3N=NCH3
• Other names: Azomethane; (CH3N)2; 1,2-Dimethyldiazene; Dimethyldiazene
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Phase change data
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
  • Switch to SI units

Gas phase ion energetics data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C₂H₆N₂⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   C_2h     Symmetry Number σ = 2

Source: Shimanouchi, 1972

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frost, Lee, et al., 1976
Frost, D.C.; Lee, S.T.; McDowell, C.A.; Westwood, N.P.C., The photoelectron spectra of diazene, diazene-d2, trans-methyldiazene, J. Chem. Phys., 1976, 64, 4719. [all data]

Prasil and Forst, 1968
Prasil, Z.; Forst, W., Mass spectrometry of azomethane, J. Am. Chem. Soc., 1968, 90, 3344. [all data]

Gowenlock, Majer, et al., 1962
Gowenlock, B.G.; Majer, J.R.; Snelling, D.R., Bond dissociation energies in some azo compounds, J. Chem. Soc. Faraday Trans., 1962, 58, 670. [all data]

Rao, 1975
Rao, C.N.R., Lone-pair ionization bands of chromophores in the photoelectron spectra of organic molecules, Indian J. Chem., 1975, 13, 950. [all data]

Koenig, Balle, et al., 1975
Koenig, T.; Balle, T.; Snell, W., Helium(I) photoelectron spectra of organic radicals, J. Am. Chem. Soc., 1975, 97, 662. [all data]

Foster and Beauchamp, 1972
Foster, M.S.; Beauchamp, J.L., Gas-phase ion chemistry of azomethane by ion cyclotron resonance spectroscopy, J. Am. Chem. Soc., 1972, 94, 2425. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]

Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.