Methane-d3,(methylthio)
- Formula: C2H3D3S
- Molecular weight: 65.153
- IUPAC Standard InChI: InChI=1S/C2H6S/c1-3-2/h1-2H3/i1D3
- IUPAC Standard InChIKey: QMMFVYPAHWMCMS-FIBGUPNXSA-N
- CAS Registry Number: 4752-12-9
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference |
|---|---|---|
| 8.7 ± 0.1 | EI | Keyes and Harrson, 1968 |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| CD3S+ | 11.15 | CH3 | EI | Gowenlock, Kay, et al., 1963 | |
| CHD2S+ | 11.55 | CH2D | EI | Gowenlock, Kay, et al., 1963 | |
| CH2DS+ | 11.05 | CHD2 | EI | Gowenlock, Kay, et al., 1963 | |
| CH3+ | 13.1 | ? | EI | Gowenlock, Kay, et al., 1963 | |
| CH3S+ | 11.0 | CD3 | EI | Gowenlock, Kay, et al., 1963 | |
| C2D3+ | 12.1 | ? | EI | Gowenlock, Kay, et al., 1963 | |
| C2HD2+ | 13.5 | ? | EI | Gowenlock, Kay, et al., 1963 | |
| C2H2D+ | 15.05 | ? | EI | Gowenlock, Kay, et al., 1963 | |
| C2H3+ | 16.7 | ? | EI | Gowenlock, Kay, et al., 1963 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Keyes and Harrson, 1968
Keyes, B.G.; Harrson, A.G.,
The fragmentation of aliphatic sulfur compounds by electron impact,
J. Am. Chem. Soc., 1968, 90, 5671. [all data]
Gowenlock, Kay, et al., 1963
Gowenlock, B.G.; Kay, J.; Majer, J.R.,
Electron impact studies of some sulphides and disulphides,
J. Chem. Soc. Faraday Trans., 1963, 59, 2463. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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