Thiophenol, TMS derivative
- Formula: C9H14SSi
- Molecular weight: 182.358
- IUPAC Standard InChI: InChI=1S/C9H14SSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3
- IUPAC Standard InChIKey: VJMQFIRIMMSSRW-UHFFFAOYSA-N
- CAS Registry Number: 4551-15-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Silane, trimethyl(phenylthio)-; Phenylthiotrimethylsilane; Phenyltrimethylsilyl sulfide; S-Trimethylsilylthiophenol
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.3 ± 0.1 | EI | Distefano, Ricci, et al., 1974 | LLK |
| 8.67 ± 0.05 | PE | Distefano, Pignataro, et al., 1974 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C3H9Si+ | 10.2 ± 0.1 | ? | EI | Distefano, Ricci, et al., 1974 | LLK |
| C8H11SiS+ | 9.9 ± 0.1 | CH3 | EI | Distefano, Ricci, et al., 1974 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Distefano, Ricci, et al., 1974
Distefano, G.; Ricci, A.; Danieli, R.; Foffani, A.; Innorta, G.; Torroni, S.,
Mass spectrometric evidence for p π-d π bonding between sulfur and the Group IVB elements,
J. Organomet. Chem., 1974, 65, 205. [all data]
Distefano, Pignataro, et al., 1974
Distefano, G.; Pignataro, S.; Ricci, A.; Colonna, F.P.; Pietropaolo, D.,
Interactions of π-orbitals with the group IV elements studied by ionization energy measurements,
Ann. Chim., 1974, 64, 153. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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