Tetrakis(diethylamino)titanium


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-722.8 ± 8.7kJ/molReviewMartinho Simões 
Δfliquid-505. ± 18.kJ/molReviewMartinho Simões 
Δfliquid-486.9 ± 5.9kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1461.2 ± 3.1 kJ/mol for the enthalpy of formation of Ti(OEt)4(l)
Δfliquid-498.0 ± 7.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1579.0 ± 3.9 kJ/mol for the enthalpy of formation of Ti(O-i-Pr)4(l)
Quantity Value Units Method Reference Comment
Δcliquid-12452. ± 18.kJ/molCC-SBMakhailov, Baev, et al., 1986 
Δcliquid-12234.0 ± 8.4kJ/molCC-SBKol'yakova, Rabinovich, et al., 1971Please also see Pedley and Rylance, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap94.6 ± 4.0kJ/molCC-SBBaev, Mikhailov, et al., 1985 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
6.83PEGibbins, Lappert, et al., 1975Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Makhailov, Baev, et al., 1986
Makhailov, V.E.; Baev, A.K.; Sachek, A.I.; Al'khimovich, V.M., Zh. Fiz. Khim., 1986, 60, 2306. [all data]

Kol'yakova, Rabinovich, et al., 1971
Kol'yakova, G.M.; Rabinovich, I.B.; Vyazanken, N.S., Dokl. Akad. Nauk SSSR, 1971, 200, 735. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Baev, Mikhailov, et al., 1985
Baev, A.K.; Mikhailov, V.E.; Baev, A.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1985, 28, 115. [all data]

Gibbins, Lappert, et al., 1975
Gibbins, S.G.; Lappert, M.F.; Pedley, J.B.; Sharp, G.J., Bonding studies of transition-metal complexes. Part II. Helium-I photoelectron spectra of homoleptic d0, d1, and d10 tetrakis(dialkylamides) of transition group 4B metals tungsten hexakis(dimethylamide), J. Chem. Soc. Dalton Trans., 1975, 72. [all data]


Notes

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