Tris(dimethylamino)borane
- Formula: C6H18BN3
- Molecular weight: 143.038
- IUPAC Standard InChIKey: SOLWORTYZPSMAK-UHFFFAOYSA-N
- CAS Registry Number: 4375-83-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: B(N(CH3)2)3; Boranetriamine, hexamethyl-
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.75 | EI | Lappert, Litzow, et al., 1970 | RDSH |
7.57 ± 0.05 | EI | Lappert, Pedley, et al., 1966 | RDSH |
7.9 ± 0.1 | EI | Baldwin, Lappert, et al., 1965 | RDSH |
7.60 | PE | King, Krishnamurthy, et al., 1972 | Vertical value; LLK |
UV/Visible spectrum
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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Source | Fuss, 1974 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 16898 |
Instrument | McPnerson 225 |
References
Go To: Top, Gas phase ion energetics data, UV/Visible spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lappert, Litzow, et al., 1970
Lappert, M.F.; Litzow, M.R.; Pedley, J.B.; Riley, P.N.K.; Spalding, T.R.; Tweedale, A.,
Bonding studies of compounds of boron and the group IV elements. Part III.First ionisation potentials of some simple boron compounds by electron impact and by a new empirical molecular orbital method,
J. Chem. Soc. A, 1970, 2320. [all data]
Lappert, Pedley, et al., 1966
Lappert, M.F.; Pedley, J.B.; Riley, P.N.K.; Tweedale, A.,
Ionisation potentials and electronic spectra of halogeno- and amino-boranes, and a study of some redistribution reactions,
Chem. Commun., 1966, 788. [all data]
Baldwin, Lappert, et al., 1965
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Riley, P.N.K.; Sedgwick, R.D.,
Ionisation potentials and π-bonding in the series ClnB(NMe2)3-n,
Inorg. Nucl. Chem. Letters, 1965, 1, 57. [all data]
King, Krishnamurthy, et al., 1972
King, G.H.; Krishnamurthy, S.S.; Lappert, M.F.; Pedley, J.B.,
Bonding studies of compounds of boron and the Group 4 elements. Part 9. Photoelectron spectra and bonding studies of halogeno-, dimethylamino-, and methyl-boranes, BX3 and BX2Y,
Faraday Discuss. Chem. Soc., 1972, 54, 70. [all data]
Fuss, 1974
Fuss, W.,
Z. Naturforsch., 1974, 29b, 514. [all data]
Notes
Go To: Top, Gas phase ion energetics data, UV/Visible spectrum, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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