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Tris(dimethylamino)borane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.75EILappert, Litzow, et al., 1970RDSH
7.57 ± 0.05EILappert, Pedley, et al., 1966RDSH
7.9 ± 0.1EIBaldwin, Lappert, et al., 1965RDSH
7.60PEKing, Krishnamurthy, et al., 1972Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lappert, Litzow, et al., 1970
Lappert, M.F.; Litzow, M.R.; Pedley, J.B.; Riley, P.N.K.; Spalding, T.R.; Tweedale, A., Bonding studies of compounds of boron and the group IV elements. Part III.First ionisation potentials of some simple boron compounds by electron impact and by a new empirical molecular orbital method, J. Chem. Soc. A, 1970, 2320. [all data]

Lappert, Pedley, et al., 1966
Lappert, M.F.; Pedley, J.B.; Riley, P.N.K.; Tweedale, A., Ionisation potentials and electronic spectra of halogeno- and amino-boranes, and a study of some redistribution reactions, Chem. Commun., 1966, 788. [all data]

Baldwin, Lappert, et al., 1965
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Riley, P.N.K.; Sedgwick, R.D., Ionisation potentials and «pi»-bonding in the series ClnB(NMe2)3-n, Inorg. Nucl. Chem. Letters, 1965, 1, 57. [all data]

King, Krishnamurthy, et al., 1972
King, G.H.; Krishnamurthy, S.S.; Lappert, M.F.; Pedley, J.B., Bonding studies of compounds of boron and the Group 4 elements. Part 9. Photoelectron spectra and bonding studies of halogeno-, dimethylamino-, and methyl-boranes, BX3 and BX2Y, Faraday Discuss. Chem. Soc., 1972, 54, 70. [all data]


Notes

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