Phosphine, tris(trifluoromethyl)-

• Formula: C₃F₉P
• Molecular weight: 237.9915
• IUPAC Standard InChI: InChI=1S/C3F9P/c4-1(5,6)13(2(7,8)9)3(10,11)12 Copy

  
• IUPAC Standard InChIKey: MXLDRFIVBLWESA-UHFFFAOYSA-N Copy
• CAS Registry Number: 432-04-2
• Chemical structure:
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• Other names: Tris(trifluoromethyl)phosphine
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• Information on this page:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Phase change data
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R., Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect, J. Fluorine Chem., 1982, 19, 349. [all data]

Cullen and Frost, 1962
Cullen, W.R.; Frost, D.C., Ionization potentials of some perfluoroalkyl arsines, Can. J. Chem., 1962, 40, 390. [all data]

Cowley, Dewar, et al., 1975
Cowley, A.H.; Dewar, M.J.S.; Goodman, D.W., Molecular photoelectron spectroscopic studies of some trifluoromethyl-substituted phosphines and chlorophosphines, J. Am. Chem. Soc., 1975, 97, 3653. [all data]

Cowley, Dewar, et al., 1974
Cowley, A.H.; Dewar, M.J.S.; Goodman, D.W.; Padolina, M.C., A photoelectron spectroscopic study of polyphosphines. The question of pπ:dπ bonding, J. Am. Chem. Soc., 1974, 96, 3666. [all data]

Cowley, Dewar, et al., 1974, 2
Cowley, A.H.; Dewar, M.J.S.; Gilje, J.W.; Goodman, D.W.; Schweiger, J.R., Relationship between the photoelectron spectra and torsional barriers of aminophosphines, J. Chem. Soc., Chem. Commun., 1974, 340. [all data]

Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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