Tris(trifluoromethyl)amine
- Formula: C3F9N
- Molecular weight: 221.0244
- IUPAC Standard InChI: InChI=1S/C3F9N/c4-1(5,6)13(2(7,8)9)3(10,11)12
- IUPAC Standard InChIKey: YPJHKJFGSWJFTM-UHFFFAOYSA-N
- CAS Registry Number: 432-03-1
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 23.9 | 248. | A | Stephenson and Malanowski, 1987 | Based on data from 193. to 263. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.7 | PE | Elbel, Dieck, et al., 1982 | LBLHLM |
| 11.7 | PE | Burger, Pawelke, et al., 1982 | LBLHLM |
| 12.55 | PE | Elbel, Dieck, et al., 1982 | Vertical value; LBLHLM |
| 12.52 | PE | Burger, Pawelke, et al., 1982 | Vertical value; LBLHLM |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R.,
Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect,
J. Fluorine Chem., 1982, 19, 349. [all data]
Burger, Pawelke, et al., 1982
Burger, H.; Pawelke, G.; Dammel, R.; Bock, H.,
Effects of fluorine substitution on methyl amines,
J. Fluorine Chem., 1982, 19, 565. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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