CdCH3

• Formula: CH₃Cd
• Molecular weight: 127.446
• CAS Registry Number: 42217-97-0
• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Options:
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C₂H₆Cd (g) = CH₃Cd (g) +  (g)

By formula: C₂H₆Cd (g) = CH₃Cd (g) + CH₄ (g)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C

State:   A

State:   X

Additional references: Jacox, 1994, page 231; Jacox, 1998, page 268; Jacox, 2003, page 250

Notes

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Jackson, 1989
Jackson, R.L., Chem. Phys. Lett., 1989, 163, 315. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Young, Gosavi, et al., 1973
Young, P.J.; Gosavi, R.K.; Connor, J.; Strausz, O.P.; Gunning, H.E., Ultraviolet absorption spectra of CdCH3, ZnCH3, and TeCH3, J. Chem. Phys., 1973, 58, 12, 5280, https://doi.org/10.1063/1.1679141 . [all data]

Ellis, Robles, et al., 1992
Ellis, A.M.; Robles, E.S.J.; Miller, T.A., Dispersed fluorescence spectroscopy and fluorescence lifetime measurements of excited vibrational levels of CdCH3, Chem. Phys. Lett., 1992, 190, 6, 599, https://doi.org/10.1016/0009-2614(92)85196-H . [all data]

Yu, Youngs, et al., 1986
Yu, C.F.; Youngs, F.; Tsukiyama, K.; Bersohn, R.; Preses, J., Photodissociation dynamics of cadmium and zinc dimethyl, J. Chem. Phys., 1986, 85, 3, 1382, https://doi.org/10.1063/1.451226 . [all data]

Suto, Ye, et al., 1988
Suto, M.; Ye, C.; Lee, L.C., Quantitative absorption and fluorescence spectroscopy of Cd(CH3)2 in vacuum ultraviolet, J. Chem. Phys., 1988, 89, 1, 160, https://doi.org/10.1063/1.455499 . [all data]

Ibuki, Hiraya, et al., 1990
Ibuki, T.; Hiraya, A.; Shobatake, K., Photoexcitation of M(CH3)2 (M=Zn, Cd, Hg) compounds in the 106--270 nm region, J. Chem. Phys., 1990, 92, 5, 2797, https://doi.org/10.1063/1.457926 . [all data]

Penner, Amirav, et al., 1991
Penner, A.; Amirav, A.; Bersohn, R., Emission spectrum of CdCH3, Chem. Phys. Lett., 1991, 176, 2, 147, https://doi.org/10.1016/0009-2614(91)90146-Z . [all data]

Robles, Ellis, et al., 1991
Robles, E.S.J.; Ellis, A.M.; Miller, T.A., Laser-induced fluorescence spectra of the cold radicals, ZnCH3 and CdCH3, and their inert-gas complexes, X«58872»CdCH3 (X = He, Ne, Ar, Kr, Xe), Chem. Phys. Lett., 1991, 178, 2-3, 185, https://doi.org/10.1016/0009-2614(91)87054-F . [all data]

Cerny, Tan, et al., 1993
Cerny, T.M.; Tan, X.Q.; Williamson, J.M.; Robles, E.S.J.; Ellis, A.M.; Miller, T.A., High resolution electronic spectroscopy of ZnCH3 and CdCH3, J. Chem. Phys., 1993, 99, 12, 9376, https://doi.org/10.1063/1.465521 . [all data]

Tan, Cerny, et al., 1994
Tan, X.Q.; Cerny, T.M.; Williamson, J.M.; Miller, T.A., Hyperfine structure in the electronic spectra of the CdH and CdCH3 radicals, J. Chem. Phys., 1994, 101, 8, 6396, https://doi.org/10.1063/1.468396 . [all data]

Panov, Powers, et al., 1998
Panov, S.I.; Powers, D.E.; Miller, T.A., The spectroscopy of the CdCH[sub 3] radical and its positive ion, J. Chem. Phys., 1998, 108, 4, 1335, https://doi.org/10.1063/1.475506 . [all data]

Pushkarsky, Barckholtz, et al., 1999
Pushkarsky, M.B.; Barckholtz, T.A.; Miller, T.A., J. Ch3m. Phys., 1999, 110, 2016. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, NIST Free Links, References

• Symbols used in this document:
  

  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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