2,2,3,3,3-Pentafluoro-1-propanol

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
11.2PERobin and Kuebler, 1973LLK
11.68PERobin and Kuebler, 1973Vertical value; LLK

De-protonation reactions

C3H2F5O- + Hydrogen cation = 2,2,3,3,3-Pentafluoro-1-propanol

By formula: C3H2F5O- + H+ = C3H3F5O

Quantity Value Units Method Reference Comment
Deltar1487. ± 26.kJ/molG+TSDawson and Jennings, 1977gas phase; Between (CF3)2CHOH, CF3CH2OH; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar1459. ± 25.kJ/molIMRBDawson and Jennings, 1977gas phase; Between (CF3)2CHOH, CF3CH2OH; value altered from reference due to change in acidity scale; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Robin and Kuebler, 1973
Robin, M.B.; Kuebler, N.A., Excited electronic states of the simple alcohols, J. Electron Spectrosc. Relat. Phenom., 1973, 1, 13. [all data]

Dawson and Jennings, 1977
Dawson, J.H.J.; Jennings, K.R., Relative gas phase acidities of some fluoroalcohols, Int. J. Mass Spectrom. Ion Phys., 1977, 25, 47. [all data]


Notes

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