Phosphine, (trifluoromethyl)-
- Formula: CH2F3P
- Molecular weight: 101.9956
- IUPAC Standard InChI: InChI=1S/CH2F3P/c2-1(3,4)5/h5H2
- IUPAC Standard InChIKey: QQAHNNMLPUNNNJ-UHFFFAOYSA-N
- CAS Registry Number: 420-52-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Trifluoromethylphosphine
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.15 | PE | Elbel, Dieck, et al., 1982 | Vertical value; LBLHLM |
| 11.15 ± 0.05 | PE | Demuth, 1977 | Vertical value; LLK |
| 11.18 | PE | Cowley, Dewar, et al., 1975 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R.,
Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect,
J. Fluorine Chem., 1982, 19, 349. [all data]
Demuth, 1977
Demuth, R.,
Photoelektronenspektren von einigen Trihalogensilylphosphanen und -arsanen X3SiER2 (X = F, Cl; E = N, P, As; R = H, CH3),
Z. Naturforsch. B:, 1977, 32, 1252. [all data]
Cowley, Dewar, et al., 1975
Cowley, A.H.; Dewar, M.J.S.; Goodman, D.W.,
Molecular photoelectron spectroscopic studies of some trifluoromethyl-substituted phosphines and chlorophosphines,
J. Am. Chem. Soc., 1975, 97, 3653. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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