Ethane, 1,1,1-trifluoro-

• Formula: C₂H₃F₃
• Molecular weight: 84.0404
• IUPAC Standard InChI: InChI=1S/C2H3F3/c1-2(3,4)5/h1H3 Copy

  
• IUPAC Standard InChIKey: UJPMYEOUBPIPHQ-UHFFFAOYSA-N Copy
• CAS Registry Number: 420-46-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Methylfluoroform; 1,1,1-Trifluoroethane; CH3CF3; Freon 143a; FC 143a; Fluorocarbon FC143a; R 143a; 1,1,1-Trifluoroform
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Fluid Properties
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Entropy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Enthalpy of fusion

Enthalpy of phase transition

Entropy of phase transition

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  =  + 

By formula: C₂H₃F₃ + I₂ = HI + C₂H₂F₃I

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu and Rodgers, 1974
Wu, E.; Rodgers, A.S., Thermochemistry of gas-phase equilibrium CF₃CH₃ + I₂ = CF₃CH₂I + HI. The carbon-hydrogen bond dissociation energy in 1,1,1-trifluoroethane and the heat of formation of the 2,2,2-trifluoroethyl radical, J. Phys. Chem., 1974, 78, 2315-2317. [all data]

Kolesov and Papina, 1983
Kolesov, V.P.; Papina, T.S., Thermochemistry of Haloethanes, Russ. Chem. Rev., 1983, 52, 425. [all data]

Kolesov, Martynov, et al., 1965
Kolesov, V.P.; Martynov, A.M.; Skuratov, S.M., Standard enthalpy of formation of 1,1,1-trifluoroethane, Russ. J. Phys. Chem. (Engl. Transl.), 1965, 39, 223-225. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Henne and Renoll, 1936
Henne, A.L.; Renoll, M.W., J. Am. Chem. Soc., 1936, 58, 889. [all data]

Russell, Golding, et al., 1944
Russell, H.K.; Golding, D.R.; Yost, D.M., The heat capacity, heat of transition, fusion & vaporization, Vapor press. and entropy of 1,1,1-trifluoroethane, J. Am. Chem. Soc., 1944, 66, 16. [all data]

Fujiwara, Nakamura, et al., 1998
Fujiwara, K.; Nakamura, S.; Noguchi, M., Critical Parameters and Vapor Pressure Measurements for 1,1,1-Trifluoroethane (R-143a), J. Chem. Eng. Data, 1998, 43, 55-9. [all data]

Aoyama, Kishizawa, et al., 1996
Aoyama, H.; Kishizawa, G.; Sato, H.; Watanabe, K., Vapor-Liquid Coexistence Curves in the Critical Region and the Critical Temperatures and Densities of 1,1,1,2-Tetrafluoroethane (R-134a), 1,1,1- Trifluoroethane (R-143a), and 1,1,1,2,3,3- Hexafluorop, J. Chem. Eng. Data, 1996, 41, 1046-1051. [all data]

Fukushima, 1993
Fukushima, M., Measurements of vapor pressure , vapor-liquid coexistence curve and critical parameters of HFC-143a, Nippon Reito Kyokai Ronbunshu, 1993, 10, 87-93. [all data]

Mears, Stahl, et al., 1955
Mears, W.H.; Stahl, R.F.; Orfeo, S.R.; Shair, R.C.; Kells, L.F.; Thompson, W.; McCann, H., Thermodynamic Properties of Halogenated Ethanes and Ethylenes, Ind. Eng. Chem., 1955, 47, 1449. [all data]

Zhang, Sato, et al., 1995
Zhang, H.-L.; Sato, H.; Watanabe, K., Vapor Pressures, Gas-Phase PVT Properties, and Second Virial Coefficients for 1,1,1-Trifluoroethane, J. Chem. Eng. Data, 1995, 40, 887-90. [all data]

Russell, Golding, et al., 1944, 2
Russell, H., Jr.; Golding, D.R.V.; Yost, D.M., The heat capacity, heats of transition, fusion and vaporization, vapor pressure and entropy of 1,1,1-trifluoroethane, J. Am. Chem. Soc., 1944, 66, 16-20. [all data]

Weber and Defibaugh, 1996
Weber, L.A.; Defibaugh, D.R., Vapor Pressures and PVT Properties of the Gas Phase of 1,1,1-Trifluoroethane, J. Chem. Eng. Data, 1996, 41, 6, 1477-1480, https://doi.org/10.1021/je9602071 . [all data]

Mears, Stahl, et al., 1955, 2
Mears, Whitney H.; Stahl, Richard F.; Orfeo, S. Robert; Shair, Robert C.; Kells, Lyman F.; Thompson, Walter; McCann, Harold, Thermodynamic Properties of Halogenated Ethanes and Ethylenes, Ind. Eng. Chem., 1955, 47, 7, 1449-1454, https://doi.org/10.1021/ie50547a052 . [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Simmie and Tschuikow-Roux, 1971
Simmie, J.M.; Tschuikow-Roux, E., Mass spectrum, appearance potentials and bond dissociation energies of 1,1,1-trifluoroethane, Int. J. Mass Spectrom. Ion Phys., 1971, 7, 41. [all data]

Sauvageau, Doucet, et al., 1974
Sauvageau, P.; Doucet, J.; Gilbert, R.; Sandorfy, C., Vacuum ultraviolet and photoelectron spectra of fluoroethanes, J. Chem. Phys., 1974, 61, 391. [all data]

Gol'denfel'd, Korostyshevskii, et al., 1973
Gol'denfel'd, I.V.; Korostyshevskii, I.Z.; Mischanchuk, B.G.; Pokrovskii, V.A., Determination of ionization potentials of atoms and molecules using a field mass spectrometer equipped with an energy analyzer, Dokl. Akad. Nauk SSSR, 1973, 213, 626. [all data]

Loguinov, Takhistov, et al., 1981
Loguinov, Y.; Takhistov, V.V.; Vatlina, L.P., Photoionization studies of substituted trimethylamines, Org. Mass Spectrom., 1981, 16, 239. [all data]

Steele and Stone, 1962
Steele, W.C.; Stone, F.G.A., An electron impact study of 1,1,1-trifluoroethane, 1,1,1-trifluoropropane and 3,3,3-trifluoropropene, J. Am. Chem. Soc., 1962, 84, 3450. [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References

• Symbols used in this document:
  

  AE	Appearance energy
  Pc	Critical pressure
  Tboil	Boiling point
  Tc	Critical temperature
  Ttriple	Triple point temperature
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔcH°gas	Enthalpy of combustion of gas at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔvapH	Enthalpy of vaporization
  ΔvapS	Entropy of vaporization
  ρc	Critical density

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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