Thiocarbonyl fluoride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
4.59196.AStephenson and Malanowski, 1987Based on data from 133. to 211. K. See also Dykyj, 1970.
4.16196.AStephenson and Malanowski, 1987Based on data from 178. to 211. K. See also Dykyj, Svoboda, et al., 1999 and Downs, 1962.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to CF2S+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
10.3EIBinnewies, Grosse, et al., 1985LBLHLM
10.52PEMines, Thomas, et al., 1973LLK
10.53 ± 0.10EIHildenbrand, 1973LLK
10.45 ± 0.01PEKroto and Suffolk, 1972LLK
10.64PEWittel, Hass, et al., 1972Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Downs, 1962
Downs, A.J., 846. Thiocarbonyl fluoride, J. Chem. Soc., 1962, 4361, https://doi.org/10.1039/jr9620004361 . [all data]

Binnewies, Grosse, et al., 1985
Binnewies, M.; Grosse, J.; Le Van, D., Reaktive E=C(p-p)π-systeme II: Massenspektrometrische untersuchun von F3CP=CF2, F3CAs=CF2, S=CF2 und Se=CF2, Phosphorus Sulfur, 1985, 21, 349. [all data]

Mines, Thomas, et al., 1973
Mines, G.W.; Thomas, R.K.; Thompson, H., The photoelectron spectra of thiocarbonyl fluoride and thiocarbonyl chloride, Proc. R. Soc. London A:, 1973, 333, 171. [all data]

Hildenbrand, 1973
Hildenbrand, D.L., Mass spectrometric studies of some gaseous sulfur fluorides, J. Phys. Chem., 1973, 77, 897. [all data]

Kroto and Suffolk, 1972
Kroto, H.W.; Suffolk, R.J., The photoelectron spectrum of and F2CS fluorine substitution shifts, Chem. Phys. Lett., 1972, 17, 213. [all data]

Wittel, Hass, et al., 1972
Wittel, K.; Hass, A.; Bock, H., Photoelektronenspektren und molekuleigenschaften, XVI. Thiocarbonylhalogenide-orbitale und ladungen, Chem. Ber., 1972, 105, 3865. [all data]


Notes

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