Methanamine, N-methyl-N-nitro-

• Formula: C₂H₆N₂O₂
• Molecular weight: 90.0812
• IUPAC Standard InChI: InChI=1S/C2H6N2O2/c1-3(2)4(5)6/h1-2H3 Copy

  
• IUPAC Standard InChIKey: XRWKADIRZXTTLH-UHFFFAOYSA-N Copy
• CAS Registry Number: 4164-28-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Dimethylnitramine; Dimethylamine, N-nitro-; s-N,N-Dimethyl nitramine; Dimethylnitroamine; N-Nitrodimethylamine; N,N-Dimethylnitramine; (CH3)2NNO2; Dimethylnitramin; DMNO; DMN; N-Nitro-DMA; NSC 137860
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• Information on this page:
  • Gas phase thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Phase change data
  • Mass spectrum (electron ionization)
  • UV/Visible spectrum
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Matyushin, V'yunova, et al., 1971
Matyushin, Yu.N.; V'yunova, I.B.; Pepekin, V.I.; Apin, A.Ya., Enthalpy of formation of the piperidyl radical, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1971, 2320-2323. [all data]

Korsunsky, Pepkin, et al., 1967
Korsunsky, B.L.; Pepkin, V.I.; Lebedev, Yu.A.; Apin, A.Ya., Thermochemical and kinetic investigation of N,N-dimethylnitrosoamine, Izv. Akad. Nauk SSSR, Ser. Khim., 1967, 525-528. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

White, Colton, et al., 1975
White, M.G.; Colton, R.J.; Lee, T.H.; Rabalais, J.W., Electronic structure of N,N-dimethylnitramine and N,N-dimethylnitrosamine from X-ray and uv electron spectroscopy, Chem. Phys., 1975, 8, 391. [all data]

Fisher and Henderson, 1967
Fisher, I.P.; Henderson, E., Mass spectrometry of free radicals, J. Chem. Soc. Faraday Trans., 1967, 63, 1342. [all data]

Gowenlock, Jones, et al., 1961
Gowenlock, B.G.; Jones, P.P.; Majer, J.R., Bond dissociation energies in some molecules containing alkyl substituted CH₃, NH₂, and OH, J. Chem. Soc. Faraday Trans., 1961, 57, 23. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy
  ΔfH°gas	Enthalpy of formation of gas at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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