(E)-CH3N=NCH3

• Formula: C₂H₆N₂
• Molecular weight: 58.0824
• IUPAC Standard InChI: InChI=1S/C2H6N2/c1-3-4-2/h1-2H3/b4-3+ Copy

  
• IUPAC Standard InChIKey: JCCAVOLDXDEODY-ONEGZZNKSA-N Copy
• CAS Registry Number: 4143-41-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Stereoisomers:
  • Diazene, dimethyl-
• Other names: (E)-Dimethyldiazene
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• Information on this page:
  • Gas phase ion energetics data
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • UV/Visible spectrum
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C₂H₆N₂⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

References

Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Foster, Williamson, et al., 1974
Foster, M.S.; Williamson, A.D.; Beauchamp, J.L., Photoionization mass spectrometry of trans-azomethane, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 429. [all data]

Brundle, Robin, et al., 1972
Brundle, C.R.; Robin, M.B.; Kuebler, N.A.; Basch, H., Perfluoro effect in photoelectron spectroscopy. I. Nonaromatic molecules, J. Am. Chem. Soc., 1972, 94, 1451. [all data]

Haselbach and Heilbronner, 1970
Haselbach, E.; Heilbronner, E., Die PhotoelektronSpektren von CH₃-CH≡CH-CH₃, CH₃-N≡CH-CH₃, CH₃-N≡N-CH₃, ein Beitrag zur Frage nach der Wechselwirkung zwischen den einsamen Elektronenpaaren der trans-konfigurierten Azogruppe, Helv. Chim. Acta, 1970, 53, 684. [all data]

Görgényi, Fekete, et al., 1989
Görgényi, M.; Fekete, Z.; Seres, L., Estimation and prediction of the retention indices of selected trans-diazenes, Chromatographia, 1989, 27, 11/12, 581-584, https://doi.org/10.1007/BF02258982 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Gas Chromatography, References

• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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