Bis(η5-cyclopentadienyl)dimethyl tungsten
- Formula: C12H16W
- Molecular weight: 344.10
- CAS Registry Number: 39333-53-4
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C12H16W (cr) + 2( • 5.55
) (solution) = C10H10Cl2W (cr) + 2
(g)
By formula: C12H16W (cr) + 2(HCl • 5.55H2O) (solution) = C10H10Cl2W (cr) + 2CH4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -169.9 ± 2.3 | kJ/mol | RSC | Calado, Dias, et al., 1978 | Please also see Calhorda, Dias, et al., 1987. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
5.8 | PE | Green, Jackson, et al., 1975 | LLK |
6.0 ± 0.1 | PE | Green, Jackson, et al., 1975 | Vertical value; LLK |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Calado, Dias, et al., 1978
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V.,
J. Chem. Soc., Chem. Commun., 1978, 737.. [all data]
Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A.,
Organometallics, 1987, 6, 734. [all data]
Green, Jackson, et al., 1975
Green, J.C.; Jackson, S.E.; Higginson, B.,
Photoelectron studies of some bent bis(n-cyclopentadienyl)metal complexes. Part I. Some eighteen-electron systems with hydride, alkyl, olefin, allyl, carbonyl ligands,
J. Chem. Soc. Dalton Trans., 1975, 403. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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