CH3SiH=CH2
- Formula: C2H6Si
- Molecular weight: 58.1545
- CAS Registry Number: 38063-40-0
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 38460 | gas | 220 | 300 | Vatsa, Kumar, et al., 1996 | |||
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 38460 | Ar | Drahnak, Michl, et al., 1981 | |||||
Arrington, Klingensmith, et al., 1984 | |||||||
Maier, Mihm, et al., 1984 | |||||||
State: X
Additional references: Jacox, 1994, page 399; Jacox, 2003, page 385; Khabashesku, Kudin, et al., 1998
Notes
w | Weak |
m | Medium |
s | Strong |
vs | Very strong |
x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Vatsa, Kumar, et al., 1996
Vatsa, R.K.; Kumar, A.; Naik, P.D.; Upadhyaya, H.P., et al.,
UV spectrum and decay kinetics of transient methylsilene produced in the 193 nm photolysis of gaseous 1-methyl-1-silacyclobutane,
Chem. Phys. Lett., 1996, 255, 1-3, 129, https://doi.org/10.1016/0009-2614(96)00342-9
. [all data]
Drahnak, Michl, et al., 1981
Drahnak, T.J.; Michl, J.; West, R.,
Photoisomerization of dimethylsilylene to 2-silapropene and thermal reversion to dimethylsilylene,
J. Am. Chem. Soc., 1981, 103, 7, 1845, https://doi.org/10.1021/ja00397a047
. [all data]
Arrington, Klingensmith, et al., 1984
Arrington, C.A.; Klingensmith, K.A.; West, R.; Michl, J.,
Polarized infrared spectroscopy of matrix-isolated dimethylsilylene and 1-methylsilene,
J. Am. Chem. Soc., 1984, 106, 3, 525, https://doi.org/10.1021/ja00315a010
. [all data]
Maier, Mihm, et al., 1984
Maier, G.; Mihm, G.; Reisenauer, H.P.; Littmann, D.,
Hetero-π-Systeme, 9. Über die Beziehungen zwischen Silaethenen und Methylsilylenen,
Chem. Ber., 1984, 117, 7, 2369, https://doi.org/10.1002/cber.19841170709
. [all data]
Raabe, Vancik, et al., 1986
Raabe, G.; Vancik, H.; West, R.; Michl, J.,
IR transition moment directions in matrix-isolated dimethylsilylene and 1-methylsilene,
J. Am. Chem. Soc., 1986, 108, 4, 671, https://doi.org/10.1021/ja00264a017
. [all data]
Reisenauer, Mihm, et al., 1982
Reisenauer, H.P.; Mihm, G.; Maier, G.,
Reversible Photoisomerisierung zwischen Silaethenen und Methylsilylenen (Methylsilandiylen),
Angew. Chem., 1982, 94, 11, 864, https://doi.org/10.1002/ange.19820941110
. [all data]
Trommer, Sander, et al., 1993
Trommer, M.; Sander, W.; Patyk, A.,
Oxidation of methylsilenes with molecular oxygen. A matrix isolation study,
J. Am. Chem. Soc., 1993, 115, 25, 11775, https://doi.org/10.1021/ja00078a016
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Khabashesku, Kudin, et al., 1998
Khabashesku, V.N.; Kudin, K.N.; Margrave, J.L.,
Vibrational analysis of infrared spectra of matrix-isolated transient silenes on basis of density functional theory calculations,
J. Mol. Struct., 1998, 443, 1-3, 175, https://doi.org/10.1016/S0022-2860(97)00398-0
. [all data]
Notes
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