trifluoromethyl hypofluorite
- Formula: CF4O
- Molecular weight: 104.0037
- CAS Registry Number: 373-91-1
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
13.0 | PE | Robin and Kuebler, 1973 | LLK |
13.6 | PE | Robin and Kuebler, 1973 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C+ | 41. ± 1. | 4F+O? | EI | Thynne and MacNeil, 1970 | RDSH |
CF+ | 31.1 ± 0.5 | ? | EI | Thynne and MacNeil, 1970 | RDSH |
COF+ | 20.0 ± 0.3 | ? | EI | Thynne and MacNeil, 1970 | RDSH |
CF2+ | 28.0 ± 0.5 | ? | EI | Thynne and MacNeil, 1970 | RDSH |
COF2+ | 18.4 ± 0.2 | ? | EI | Thynne and MacNeil, 1970 | RDSH |
CF3+ | 14.8 ± 0.2 | OF? | EI | Thynne and MacNeil, 1970 | RDSH |
COF3+ | 16.1 ± 0.2 | F | EI | Thynne and MacNeil, 1970 | RDSH |
F+ | 36. ± 1. | ? | EI | Thynne and MacNeil, 1970 | RDSH |
OF+ | 38. ± 1. | ? | EI | Thynne and MacNeil, 1970 | RDSH |
O+ | 36. ± 1. | ? | EI | Thynne and MacNeil, 1970 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Robin and Kuebler, 1973
Robin, M.B.; Kuebler, N.A.,
Excited electronic states of the simple alcohols,
J. Electron Spectrosc. Relat. Phenom., 1973, 1, 13. [all data]
Thynne and MacNeil, 1970
Thynne, J.C.J.; MacNeil, K.A.G.,
Ionisation and dissociation of carbonyl fluoride and trifluoromethyl hypofluorite by electron impact,
Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 95. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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