Dimethyl trisulfide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.73 ± 0.03PECullen, Frost, et al., 1969RDSH
8.80 ± 0.15EIHobrock and Kiser, 1963RDSH
8.85PEChang, Young, et al., 1986Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHS+14.5 ± 0.3?EIHobrock and Kiser, 1963RDSH
CH2S+13.4 ± 0.3?EIHobrock and Kiser, 1963RDSH
CH3S+12.9 ± 0.2?EIHobrock and Kiser, 1963RDSH
CH3S2+12.3 ± 0.2?EIHobrock and Kiser, 1963RDSH
CH3S3+11.4 ± 0.2CH3EIHobrock and Kiser, 1963RDSH
CH4S2+10.8 ± 0.2?EIHobrock and Kiser, 1963RDSH
S2+14.4 ± 0.3?EIHobrock and Kiser, 1963RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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on behalf of the United States of America. All rights reserved.
NIST MS number 2588

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References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cullen, Frost, et al., 1969
Cullen, W.R.; Frost, D.C.; Vroom, D.A., Ionization potentials of some sulfur compounds, Inorg. Chem., 1969, 8, 1803. [all data]

Hobrock and Kiser, 1963
Hobrock, B.G.; Kiser, R.W., Electron impact investigations of sulfur compounds. III. 2-Thiapropane, 3-thiapentane, and 2,3,4-trithiapentane, J. Phys. Chem., 1963, 67, 1283. [all data]

Chang, Young, et al., 1986
Chang, F.C.; Young, V.Y.; Prather, J.W.; Cheng, K.L., Study of methyl chalcogen compounds with ultraviolet photoelectron spectroscopy, J. Electron Spectrosc. Relat. Phenom., 1986, 40, 363. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References